Chiral amorphous metal–organic polyhedra used as the stationary phase for high-resolution gas chromatography separations

Bo Tang, Chenyu Sun, Wei Wang, Lina Geng, Liquan Sun, Aiqin Luo*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

Herein, we describe a new chiral amorphous metal–organic polyhedra used as the stationary phase for high-resolution gas chromatography (GC). The chiral stationary phase was coated onto a capillary column via a dynamic coating process and investigated for a variety of compounds. The experimental results showed that the chiral stationary phase exhibits good selectivity for linear alkanes, linear alcohols, polycyclic aromatic hydrocarbons, isomers, and chiral compounds. In addition, the column has the advantages of high column efficiency and short analysis time. The present work indicated that amorphous metal–organic polyhedra have great potential for application as a new type of stationary phase for GC.

Original languageEnglish
Pages (from-to)1178-1185
Number of pages8
JournalChirality
Volume32
Issue number9
DOIs
Publication statusPublished - 1 Sept 2020

Keywords

  • amorphous metal–organic polyhedra
  • chiral recognition
  • chiral stationary phases
  • gas chromatography

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