Asymmetric reactions catalyzed by chiral titanium complexes

Fuxue Chen; Xiaoming Feng; Yaozhong Jiang

Asymmetric reactions catalyzed by chiral titanium complexes

Fuxue Chen, Xiaoming Feng^*, Yaozhong Jiang

^*Corresponding author for this work

Research output: Contribution to journal › Review article › peer-review

14 Citations (Scopus)

Abstract

This presentation reviewed some of our recent progress in asymmetric reactions catalyzed by chiral Ti(IV) complexes, including asymmetric oxa-Diels-Alder reaction(up to 99%ee), asymmetric oxidation of sulfides for sulfoxides (up to 96% ee), enantioselective silylcyanation of aldehydes (up to 87% ee) and ketones (up to 69% ee). The influence of ligand structure, substrate, amount of catalyst, counter ion, solvent, temperature, and other conditions on the reactivity and selectivity were discussed. Some mechanistic insights were also presented.

Original language	English
Pages (from-to)	21-31
Number of pages	11
Journal	Arkivoc
Volume	2003
Issue number	2
Publication status	Published - 2003
Externally published	Yes

Keywords

Asymmetric reactions
Catalysis
Chiral titanium complexes

Cite this

Chen, F., Feng, X., & Jiang, Y. (2003). Asymmetric reactions catalyzed by chiral titanium complexes. Arkivoc, 2003(2), 21-31.

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abstract = "This presentation reviewed some of our recent progress in asymmetric reactions catalyzed by chiral Ti(IV) complexes, including asymmetric oxa-Diels-Alder reaction(up to 99%ee), asymmetric oxidation of sulfides for sulfoxides (up to 96% ee), enantioselective silylcyanation of aldehydes (up to 87% ee) and ketones (up to 69% ee). The influence of ligand structure, substrate, amount of catalyst, counter ion, solvent, temperature, and other conditions on the reactivity and selectivity were discussed. Some mechanistic insights were also presented.",

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T1 - Asymmetric reactions catalyzed by chiral titanium complexes

AU - Chen, Fuxue

AU - Feng, Xiaoming

AU - Jiang, Yaozhong

PY - 2003

Y1 - 2003

N2 - This presentation reviewed some of our recent progress in asymmetric reactions catalyzed by chiral Ti(IV) complexes, including asymmetric oxa-Diels-Alder reaction(up to 99%ee), asymmetric oxidation of sulfides for sulfoxides (up to 96% ee), enantioselective silylcyanation of aldehydes (up to 87% ee) and ketones (up to 69% ee). The influence of ligand structure, substrate, amount of catalyst, counter ion, solvent, temperature, and other conditions on the reactivity and selectivity were discussed. Some mechanistic insights were also presented.

AB - This presentation reviewed some of our recent progress in asymmetric reactions catalyzed by chiral Ti(IV) complexes, including asymmetric oxa-Diels-Alder reaction(up to 99%ee), asymmetric oxidation of sulfides for sulfoxides (up to 96% ee), enantioselective silylcyanation of aldehydes (up to 87% ee) and ketones (up to 69% ee). The influence of ligand structure, substrate, amount of catalyst, counter ion, solvent, temperature, and other conditions on the reactivity and selectivity were discussed. Some mechanistic insights were also presented.

KW - Asymmetric reactions

KW - Catalysis

KW - Chiral titanium complexes

UR - http://www.scopus.com/inward/record.url?scp=17044414137&partnerID=8YFLogxK

M3 - Review article

AN - SCOPUS:17044414137

SN - 1551-7004

VL - 2003

SP - 21

EP - 31

JO - Arkivoc

JF - Arkivoc

IS - 2

ER -

Asymmetric reactions catalyzed by chiral titanium complexes

Abstract

Keywords

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