An unprecedented decanuclear GdIII cluster for magnetic refrigeration

Sui Jun Liu; Jiong Peng Zhao; Jun Tao; Ji Min Jia; Song De Han; Yue Li; Yan Cong Chen; Xian He Bu

doi:10.1021/ic400487m

An unprecedented decanuclear Gd^III cluster for magnetic refrigeration

Sui Jun Liu, Jiong Peng Zhao, Jun Tao, Ji Min Jia, Song De Han, Yue Li, Yan Cong Chen, Xian He Bu^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

98 Citations (Scopus)

Abstract

An unprecedented decanuclear Gd^III cluster composed of the [Gd₁₀(μ₃-OH)₈]²²⁺ core has been hydrothermally synthesized. Magnetic analyses indicate that this complex shows weak antiferromagnetic behavior with a relatively large magnetocaloric effect (-ΔS_m^max = 31.22 J kg^-1 K^-1).

Original language	English
Pages (from-to)	9163-9165
Number of pages	3
Journal	Inorganic Chemistry
Volume	52
Issue number	16
DOIs	https://doi.org/10.1021/ic400487m
Publication status	Published - 19 Aug 2013
Externally published	Yes

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10.1021/ic400487m

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title = "An unprecedented decanuclear GdIII cluster for magnetic refrigeration",

abstract = "An unprecedented decanuclear GdIII cluster composed of the [Gd10(μ3-OH)8]22+ core has been hydrothermally synthesized. Magnetic analyses indicate that this complex shows weak antiferromagnetic behavior with a relatively large magnetocaloric effect (-ΔSmmax = 31.22 J kg-1 K-1).",

author = "Liu, {Sui Jun} and Zhao, {Jiong Peng} and Jun Tao and Jia, {Ji Min} and Han, {Song De} and Yue Li and Chen, {Yan Cong} and Bu, {Xian He}",

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month = aug,

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doi = "10.1021/ic400487m",

language = "English",

volume = "52",

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journal = "Inorganic Chemistry",

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T1 - An unprecedented decanuclear GdIII cluster for magnetic refrigeration

AU - Liu, Sui Jun

AU - Zhao, Jiong Peng

AU - Tao, Jun

AU - Jia, Ji Min

AU - Han, Song De

AU - Li, Yue

AU - Chen, Yan Cong

AU - Bu, Xian He

PY - 2013/8/19

Y1 - 2013/8/19

N2 - An unprecedented decanuclear GdIII cluster composed of the [Gd10(μ3-OH)8]22+ core has been hydrothermally synthesized. Magnetic analyses indicate that this complex shows weak antiferromagnetic behavior with a relatively large magnetocaloric effect (-ΔSmmax = 31.22 J kg-1 K-1).

AB - An unprecedented decanuclear GdIII cluster composed of the [Gd10(μ3-OH)8]22+ core has been hydrothermally synthesized. Magnetic analyses indicate that this complex shows weak antiferromagnetic behavior with a relatively large magnetocaloric effect (-ΔSmmax = 31.22 J kg-1 K-1).

UR - http://www.scopus.com/inward/record.url?scp=84882567670&partnerID=8YFLogxK

U2 - 10.1021/ic400487m

DO - 10.1021/ic400487m

M3 - Article

C2 - 23895294

AN - SCOPUS:84882567670

SN - 0020-1669

VL - 52

SP - 9163

EP - 9165

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 16

ER -

An unprecedented decanuclear Gd^III cluster for magnetic refrigeration

Abstract

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