An α-Keggin polyoxometalate completely constructed from the late transition metal CoII as poly atom

Lanjun Dong; Xiaofang Li; Jie Cao; Wei Chu; Rudan Huang

doi:10.1039/c2dt31896b

An α-Keggin polyoxometalate completely constructed from the late transition metal Co^II as poly atom

Lanjun Dong, Xiaofang Li, Jie Cao, Wei Chu, Rudan Huang^*

^*Corresponding author for this work

Ministry of Education in China

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

We report a catalytic eight-cobalt-capped α-Keggin polyoxoazocobaltite with a highly symmetric structure completely constructed from the late transition-metal Co^II as a poly atom, [Co ₂₀(OH)₂₄(MMT)₁₂(SO₄)](NO ₃)₂·6H₂O (1) (MMT: 2-mercapto-5-methyl- 1,3,4-thiadiazole). To the best of our knowledge, this is the first homometallic Co^II magnetic cluster bearing Keggin structure. It can serve as a potential catalyst in the styrene polymerization.

Original language	English
Pages (from-to)	1342-1345
Number of pages	4
Journal	Dalton Transactions
Volume	42
Issue number	5
DOIs	https://doi.org/10.1039/c2dt31896b
Publication status	Published - 7 Feb 2013
Externally published	Yes

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title = "An α-Keggin polyoxometalate completely constructed from the late transition metal CoII as poly atom",

abstract = "We report a catalytic eight-cobalt-capped α-Keggin polyoxoazocobaltite with a highly symmetric structure completely constructed from the late transition-metal CoII as a poly atom, [Co 20(OH)24(MMT)12(SO4)](NO 3)2·6H2O (1) (MMT: 2-mercapto-5-methyl- 1,3,4-thiadiazole). To the best of our knowledge, this is the first homometallic CoII magnetic cluster bearing Keggin structure. It can serve as a potential catalyst in the styrene polymerization.",

author = "Lanjun Dong and Xiaofang Li and Jie Cao and Wei Chu and Rudan Huang",

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T1 - An α-Keggin polyoxometalate completely constructed from the late transition metal CoII as poly atom

AU - Dong, Lanjun

AU - Li, Xiaofang

AU - Cao, Jie

AU - Chu, Wei

AU - Huang, Rudan

PY - 2013/2/7

Y1 - 2013/2/7

N2 - We report a catalytic eight-cobalt-capped α-Keggin polyoxoazocobaltite with a highly symmetric structure completely constructed from the late transition-metal CoII as a poly atom, [Co 20(OH)24(MMT)12(SO4)](NO 3)2·6H2O (1) (MMT: 2-mercapto-5-methyl- 1,3,4-thiadiazole). To the best of our knowledge, this is the first homometallic CoII magnetic cluster bearing Keggin structure. It can serve as a potential catalyst in the styrene polymerization.

AB - We report a catalytic eight-cobalt-capped α-Keggin polyoxoazocobaltite with a highly symmetric structure completely constructed from the late transition-metal CoII as a poly atom, [Co 20(OH)24(MMT)12(SO4)](NO 3)2·6H2O (1) (MMT: 2-mercapto-5-methyl- 1,3,4-thiadiazole). To the best of our knowledge, this is the first homometallic CoII magnetic cluster bearing Keggin structure. It can serve as a potential catalyst in the styrene polymerization.

UR - http://www.scopus.com/inward/record.url?scp=84872053418&partnerID=8YFLogxK

U2 - 10.1039/c2dt31896b

DO - 10.1039/c2dt31896b

M3 - Article

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SN - 1477-9226

VL - 42

SP - 1342

EP - 1345

JO - Dalton Transactions

JF - Dalton Transactions

IS - 5

ER -

An α-Keggin polyoxometalate completely constructed from the late transition metal Co^II as poly atom

Abstract

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