A three-dimensional coordination polymer featuring effective ferrimagnetic hydroxide-bridged manganese(II) chains

Jin Tang Li; Jun Tao; Rong Bin Huang; Lan Sun Zheng; Tan Yuen; C. L. Lin; Princy Varughese; Jing Li

doi:10.1021/ic050043m

A three-dimensional coordination polymer featuring effective ferrimagnetic hydroxide-bridged manganese(II) chains

Jin Tang Li, Jun Tao^*, Rong Bin Huang, Lan Sun Zheng, Tan Yuen, C. L. Lin, Princy Varughese, Jing Li

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

A three-dimensional coordination polymer, [Mn₃(OH) ₂Na₂(3-cnba)₆]_n (1) (3-Hcnba = 3-cyanobenzoic acid), has been synthesized by the reaction of MnCl₂, NaN₃, and 3-Hcnba in water. Its crystal structure was determined by single-crystal X-ray diffraction. Magnetic studies show that the complex behaves as a three-dimensional metamagnet built from effective ferrimagnetic Mn(II) chains in which spin moments are linked by interactions in an AF-F-AF (F = ferromagnetic and AF = antiferromagnetic) sequence in the triangular magnetic repeating unit.

Original language	English
Pages (from-to)	4448-4450
Number of pages	3
Journal	Inorganic Chemistry
Volume	44
Issue number	13
DOIs	https://doi.org/10.1021/ic050043m
Publication status	Published - 27 Jun 2005
Externally published	Yes

Access to Document

10.1021/ic050043m

Cite this

@article{29567eeae054441093d990b74d12047b,

title = "A three-dimensional coordination polymer featuring effective ferrimagnetic hydroxide-bridged manganese(II) chains",

abstract = "A three-dimensional coordination polymer, [Mn3(OH) 2Na2(3-cnba)6]n (1) (3-Hcnba = 3-cyanobenzoic acid), has been synthesized by the reaction of MnCl2, NaN3, and 3-Hcnba in water. Its crystal structure was determined by single-crystal X-ray diffraction. Magnetic studies show that the complex behaves as a three-dimensional metamagnet built from effective ferrimagnetic Mn(II) chains in which spin moments are linked by interactions in an AF-F-AF (F = ferromagnetic and AF = antiferromagnetic) sequence in the triangular magnetic repeating unit.",

author = "Li, {Jin Tang} and Jun Tao and Huang, {Rong Bin} and Zheng, {Lan Sun} and Tan Yuen and Lin, {C. L.} and Princy Varughese and Jing Li",

year = "2005",

month = jun,

day = "27",

doi = "10.1021/ic050043m",

language = "English",

volume = "44",

pages = "4448--4450",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "13",

}

TY - JOUR

T1 - A three-dimensional coordination polymer featuring effective ferrimagnetic hydroxide-bridged manganese(II) chains

AU - Li, Jin Tang

AU - Tao, Jun

AU - Huang, Rong Bin

AU - Zheng, Lan Sun

AU - Yuen, Tan

AU - Lin, C. L.

AU - Varughese, Princy

AU - Li, Jing

PY - 2005/6/27

Y1 - 2005/6/27

N2 - A three-dimensional coordination polymer, [Mn3(OH) 2Na2(3-cnba)6]n (1) (3-Hcnba = 3-cyanobenzoic acid), has been synthesized by the reaction of MnCl2, NaN3, and 3-Hcnba in water. Its crystal structure was determined by single-crystal X-ray diffraction. Magnetic studies show that the complex behaves as a three-dimensional metamagnet built from effective ferrimagnetic Mn(II) chains in which spin moments are linked by interactions in an AF-F-AF (F = ferromagnetic and AF = antiferromagnetic) sequence in the triangular magnetic repeating unit.

AB - A three-dimensional coordination polymer, [Mn3(OH) 2Na2(3-cnba)6]n (1) (3-Hcnba = 3-cyanobenzoic acid), has been synthesized by the reaction of MnCl2, NaN3, and 3-Hcnba in water. Its crystal structure was determined by single-crystal X-ray diffraction. Magnetic studies show that the complex behaves as a three-dimensional metamagnet built from effective ferrimagnetic Mn(II) chains in which spin moments are linked by interactions in an AF-F-AF (F = ferromagnetic and AF = antiferromagnetic) sequence in the triangular magnetic repeating unit.

UR - http://www.scopus.com/inward/record.url?scp=22544466702&partnerID=8YFLogxK

U2 - 10.1021/ic050043m

DO - 10.1021/ic050043m

M3 - Article

AN - SCOPUS:22544466702

SN - 0020-1669

VL - 44

SP - 4448

EP - 4450

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 13

ER -

A three-dimensional coordination polymer featuring effective ferrimagnetic hydroxide-bridged manganese(II) chains

Abstract

Access to Document

Other files and links

Fingerprint

Cite this