A homochiral 3D framework of mechanically interlocked 1D loops with solvent-dependent spin-state switching behaviors

Xiao Peng Sun; Zheng Tang; Zi Shuo Yao; Jun Tao

doi:10.1039/c9cc09063k

A homochiral 3D framework of mechanically interlocked 1D loops with solvent-dependent spin-state switching behaviors

Xiao Peng Sun, Zheng Tang, Zi Shuo Yao^*, Jun Tao

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

An atypical homochiral spin-crossover (SCO) framework (1) constructed from mechanically interlocked 1D molecular loops was prepared. Due to the flexibility of the interlocked structure, the guest solvent molecules can be reversibly exchanged. Consequently, its SCO behavior was capable of modulating between one- and two-stepped transitions in response to acetonitrile and methanol.

Original language	English
Pages (from-to)	133-136
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	1
DOIs	https://doi.org/10.1039/c9cc09063k
Publication status	Published - 2019

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title = "A homochiral 3D framework of mechanically interlocked 1D loops with solvent-dependent spin-state switching behaviors",

abstract = "An atypical homochiral spin-crossover (SCO) framework (1) constructed from mechanically interlocked 1D molecular loops was prepared. Due to the flexibility of the interlocked structure, the guest solvent molecules can be reversibly exchanged. Consequently, its SCO behavior was capable of modulating between one- and two-stepped transitions in response to acetonitrile and methanol.",

author = "Sun, {Xiao Peng} and Zheng Tang and Yao, {Zi Shuo} and Jun Tao",

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AU - Sun, Xiao Peng

AU - Tang, Zheng

AU - Yao, Zi Shuo

AU - Tao, Jun

PY - 2019

Y1 - 2019

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AB - An atypical homochiral spin-crossover (SCO) framework (1) constructed from mechanically interlocked 1D molecular loops was prepared. Due to the flexibility of the interlocked structure, the guest solvent molecules can be reversibly exchanged. Consequently, its SCO behavior was capable of modulating between one- and two-stepped transitions in response to acetonitrile and methanol.

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IS - 1

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A homochiral 3D framework of mechanically interlocked 1D loops with solvent-dependent spin-state switching behaviors

Abstract

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