2H3O · [Co8(HPO3) 9(CH3OH)3] ·2H2O: An open-framework cobalt phosphite containing extra-large 18-ring channels

Lang Zhao; Jiyang Li; Peng Chen; Guanghua Li; Jihong Yu; Ruren Xu

doi:10.1021/cm7021906

2H₃O · [Co₈(HPO₃) ₉(CH₃OH)₃] ·2H₂O: An open-framework cobalt phosphite containing extra-large 18-ring channels

Lang Zhao, Jiyang Li, Peng Chen, Guanghua Li, Jihong Yu^*, Ruren Xu

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

56 Citations (Scopus)

Abstract

The synthesis and structure of the first extra-large pore cobalt phosphite (CoHPO-CJ2) with one-dimensional channels bounded by 18 Co atoms were presented. CoHPO-CJ2 was synthesized by a solvothermal reaction of CoCl ₂.6H₂0, H₃PO₃, diethylenetriamine (DETA), ethylene glycol (EG), and H₂O. CoCl₂.6H ₂0 was first dissolved in a mixed solvent of H₂O and EG, and then H₃PO₃ was added to the reaction mixture while stirring. DETA was added to adjust the pH value of the reaction mixture to 5-6. The use of mixed solvent favored the formation of large single crystals of CoHPO-CJ2. Each Co(1)O₆ octahedron shared a face with the neighboring windmills, resulting in an infinite 2D layered structure with 18-ring window of C3v symmetry. Single crystal structural analysis reveals that the structure of CoHPO-CJ2 consists of macroionic framework and H₃O⁺ counterions.

Original language	English
Pages (from-to)	17-19
Number of pages	3
Journal	Chemistry of Materials
Volume	20
Issue number	1
DOIs	https://doi.org/10.1021/cm7021906
Publication status	Published - 8 Jan 2008
Externally published	Yes

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title = "2H3O · [Co8(HPO3) 9(CH3OH)3] ·2H2O: An open-framework cobalt phosphite containing extra-large 18-ring channels",

abstract = "The synthesis and structure of the first extra-large pore cobalt phosphite (CoHPO-CJ2) with one-dimensional channels bounded by 18 Co atoms were presented. CoHPO-CJ2 was synthesized by a solvothermal reaction of CoCl 2.6H20, H3PO3, diethylenetriamine (DETA), ethylene glycol (EG), and H2O. CoCl2.6H 20 was first dissolved in a mixed solvent of H2O and EG, and then H3PO3 was added to the reaction mixture while stirring. DETA was added to adjust the pH value of the reaction mixture to 5-6. The use of mixed solvent favored the formation of large single crystals of CoHPO-CJ2. Each Co(1)O6 octahedron shared a face with the neighboring windmills, resulting in an infinite 2D layered structure with 18-ring window of C3v symmetry. Single crystal structural analysis reveals that the structure of CoHPO-CJ2 consists of macroionic framework and H3O+ counterions.",

author = "Lang Zhao and Jiyang Li and Peng Chen and Guanghua Li and Jihong Yu and Ruren Xu",

year = "2008",

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doi = "10.1021/cm7021906",

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T1 - 2H3O · [Co8(HPO3) 9(CH3OH)3] ·2H2O

T2 - An open-framework cobalt phosphite containing extra-large 18-ring channels

AU - Zhao, Lang

AU - Li, Jiyang

AU - Chen, Peng

AU - Li, Guanghua

AU - Yu, Jihong

AU - Xu, Ruren

PY - 2008/1/8

Y1 - 2008/1/8

N2 - The synthesis and structure of the first extra-large pore cobalt phosphite (CoHPO-CJ2) with one-dimensional channels bounded by 18 Co atoms were presented. CoHPO-CJ2 was synthesized by a solvothermal reaction of CoCl 2.6H20, H3PO3, diethylenetriamine (DETA), ethylene glycol (EG), and H2O. CoCl2.6H 20 was first dissolved in a mixed solvent of H2O and EG, and then H3PO3 was added to the reaction mixture while stirring. DETA was added to adjust the pH value of the reaction mixture to 5-6. The use of mixed solvent favored the formation of large single crystals of CoHPO-CJ2. Each Co(1)O6 octahedron shared a face with the neighboring windmills, resulting in an infinite 2D layered structure with 18-ring window of C3v symmetry. Single crystal structural analysis reveals that the structure of CoHPO-CJ2 consists of macroionic framework and H3O+ counterions.

AB - The synthesis and structure of the first extra-large pore cobalt phosphite (CoHPO-CJ2) with one-dimensional channels bounded by 18 Co atoms were presented. CoHPO-CJ2 was synthesized by a solvothermal reaction of CoCl 2.6H20, H3PO3, diethylenetriamine (DETA), ethylene glycol (EG), and H2O. CoCl2.6H 20 was first dissolved in a mixed solvent of H2O and EG, and then H3PO3 was added to the reaction mixture while stirring. DETA was added to adjust the pH value of the reaction mixture to 5-6. The use of mixed solvent favored the formation of large single crystals of CoHPO-CJ2. Each Co(1)O6 octahedron shared a face with the neighboring windmills, resulting in an infinite 2D layered structure with 18-ring window of C3v symmetry. Single crystal structural analysis reveals that the structure of CoHPO-CJ2 consists of macroionic framework and H3O+ counterions.

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U2 - 10.1021/cm7021906

DO - 10.1021/cm7021906

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AN - SCOPUS:39149105291

SN - 0897-4756

VL - 20

SP - 17

EP - 19

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 1

ER -

2H₃O · [Co₈(HPO₃) ₉(CH₃OH)₃] ·2H₂O: An open-framework cobalt phosphite containing extra-large 18-ring channels

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