μ-Oxalato-k4 O 1,O 2:O 1′,O 2′-bis-{[N,N′-bis(pyridin-2- ylmethylene)propane-1,2-diamine-k4-N,N′,N′′, N′′′]copper(II)} bis(perchlorate)

Tian Fu Liu*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

In the centrosymmetric dinuclear title complex, [Cu2(C2O4)(C15H16N4)2] (ClO4)2, each CuII ion is in an elongated octa-hedral environment, coordinated by two oxalate O atoms and four N atoms from the tetra-dentate ligand. One O atom and three N atoms are in the equatorial plane, and another O atom and one N atom are in axial sites. Each copper ion is bound to two O atoms from the two different carboxyl-ate groups of the oxalate ligands, with a Cu⋯Cu distance of 5.6623 (16) Å. The anions lie on twofold rotation axes.

Original languageEnglish
Pages (from-to)m1856-m1858
JournalActa Crystallographica Section E: Structure Reports Online
Volume63
Issue number7
DOIs
Publication statusPublished - 6 Jun 2007

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