[{Zn2(HPO4)4}{Co(dien) 2}]·H3O: A zinc phosphate with multidirectional intersecting helical channels

Yu Wang; Jihong Yu; Min Guo; Ruren Xu

doi:10.1002/anie.200351643

[{Zn₂(HPO₄)₄}{Co(dien) ₂}]·H₃O: A zinc phosphate with multidirectional intersecting helical channels

Yu Wang, Jihong Yu^*, Min Guo, Ruren Xu

^*此作品的通讯作者

Jilin University

科研成果: 期刊稿件 › 文章 › 同行评审

194 引用（Scopus）

摘要

A twist in the tale: A racemic mixture of the chiral [Co(dien) ₂]Cl₃ complex has been used as a template in preparing an openframework zinc phosphate with multidirectional helical channels, consisting of alternate ZnO₄ and PO₄ tetrahedra. The framework contains 12-membered ring channels along the [100] direction, within which [Co(dien)₂]³⁺ ions are located. Each channel is enclosed by chiral interpenetrating double helices (see picture; dien=diethylenetriamine).

源语言	英语
页（从-至）	4089-4092
页数	4
期刊	Angewandte Chemie - International Edition
卷	42
期	34
DOI	https://doi.org/10.1002/anie.200351643
出版状态	已出版 - 5 9月 2003
已对外发布	是

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abstract = "A twist in the tale: A racemic mixture of the chiral [Co(dien) 2]Cl3 complex has been used as a template in preparing an openframework zinc phosphate with multidirectional helical channels, consisting of alternate ZnO4 and PO4 tetrahedra. The framework contains 12-membered ring channels along the [100] direction, within which [Co(dien)2]3+ ions are located. Each channel is enclosed by chiral interpenetrating double helices (see picture; dien=diethylenetriamine).",

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AU - Guo, Min

AU - Xu, Ruren

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AB - A twist in the tale: A racemic mixture of the chiral [Co(dien) 2]Cl3 complex has been used as a template in preparing an openframework zinc phosphate with multidirectional helical channels, consisting of alternate ZnO4 and PO4 tetrahedra. The framework contains 12-membered ring channels along the [100] direction, within which [Co(dien)2]3+ ions are located. Each channel is enclosed by chiral interpenetrating double helices (see picture; dien=diethylenetriamine).

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KW - Host-guest systems

KW - Hydrothermal synthesis

KW - Phosphates

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[{Zn2(HPO4)4}{Co(dien) 2}]·H3O: A zinc phosphate with multidirectional intersecting helical channels

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[{Zn₂(HPO₄)₄}{Co(dien) ₂}]·H₃O: A zinc phosphate with multidirectional intersecting helical channels