[{{Zn(en)2}2As6V15O 42(H2O)}2{Zn(en)2}] ·2Hen·3H2O. The First Dimeric Arsenic-Vanadium Cluster Linked by Zn(en)2 Complex Bridge

Shou Tian Zheng; Jie Zhang; Guo Yu Yang

doi:10.1246/cl.2003.810

[{{Zn(en)₂}₂As₆V₁₅O ₄₂(H₂O)}₂{Zn(en)₂}] ·2Hen·3H₂O. The First Dimeric Arsenic-Vanadium Cluster Linked by Zn(en)₂ Complex Bridge

Shou Tian Zheng, Jie Zhang, Guo Yu Yang^*

^*此作品的通讯作者

科研成果: 期刊稿件 › 文章 › 同行评审

20 引用（Scopus）

摘要

The hydrothermal reaction of VOSO₄, As₂O ₃, ZnCl₂, en (ethylenediamine), HCl, and H₂O produces [{{Zn(en)₂}₂-As₆V₁₅O ₄₂(H₂O)}₂{Zn(en)₂}] ·2Hen·3H₂O, which is the first dimeric As-V-O cluster linked by transition metal complex bridge. The structure of this compound was characterized by single crystal X-ray diffraction, elemental analysis, EPR, TGA, and IR spectrum.

源语言	英语
页（从-至）	810-811
页数	2
期刊	Chemistry Letters
卷	32
期	9
DOI	https://doi.org/10.1246/cl.2003.810
出版状态	已出版 - 5 9月 2003
已对外发布	是

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title = "[{{Zn(en)2}2As6V15O 42(H2O)}2{Zn(en)2}] ·2Hen·3H2O. The First Dimeric Arsenic-Vanadium Cluster Linked by Zn(en)2 Complex Bridge",

abstract = "The hydrothermal reaction of VOSO4, As2O 3, ZnCl2, en (ethylenediamine), HCl, and H2O produces [{{Zn(en)2}2-As6V15O 42(H2O)}2{Zn(en)2}] ·2Hen·3H2O, which is the first dimeric As-V-O cluster linked by transition metal complex bridge. The structure of this compound was characterized by single crystal X-ray diffraction, elemental analysis, EPR, TGA, and IR spectrum.",

author = "Zheng, {Shou Tian} and Jie Zhang and Yang, {Guo Yu}",

year = "2003",

month = sep,

day = "5",

doi = "10.1246/cl.2003.810",

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volume = "32",

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AU - Zheng, Shou Tian

AU - Zhang, Jie

AU - Yang, Guo Yu

PY - 2003/9/5

Y1 - 2003/9/5

N2 - The hydrothermal reaction of VOSO4, As2O 3, ZnCl2, en (ethylenediamine), HCl, and H2O produces [{{Zn(en)2}2-As6V15O 42(H2O)}2{Zn(en)2}] ·2Hen·3H2O, which is the first dimeric As-V-O cluster linked by transition metal complex bridge. The structure of this compound was characterized by single crystal X-ray diffraction, elemental analysis, EPR, TGA, and IR spectrum.

AB - The hydrothermal reaction of VOSO4, As2O 3, ZnCl2, en (ethylenediamine), HCl, and H2O produces [{{Zn(en)2}2-As6V15O 42(H2O)}2{Zn(en)2}] ·2Hen·3H2O, which is the first dimeric As-V-O cluster linked by transition metal complex bridge. The structure of this compound was characterized by single crystal X-ray diffraction, elemental analysis, EPR, TGA, and IR spectrum.

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M3 - Article

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VL - 32

SP - 810

EP - 811

JO - Chemistry Letters

JF - Chemistry Letters

IS - 9

ER -

[{{Zn(en)2}2As6V15O 42(H2O)}2{Zn(en)2}] ·2Hen·3H2O. The First Dimeric Arsenic-Vanadium Cluster Linked by Zn(en)2 Complex Bridge

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[{{Zn(en)₂}₂As₆V₁₅O ₄₂(H₂O)}₂{Zn(en)₂}] ·2Hen·3H₂O. The First Dimeric Arsenic-Vanadium Cluster Linked by Zn(en)₂ Complex Bridge