TY - JOUR
T1 - [Zn(dap)3][Zn(dap)B5O8(OH)2]2
T2 - A Novel Organic–Inorganic Hybrid Chain-Like Zincoborate Made of [B5O8(OH)2]3− Clusters and [Zn(dap)]2+ Linkers
AU - Jiang, Hang
AU - Yang, Bai Feng
AU - Wang, Guo Ming
AU - Yang, Guo Yu
N1 - Publisher Copyright:
© 2016, Springer Science+Business Media New York.
PY - 2017/5/1
Y1 - 2017/5/1
N2 - A new organic–inorganic hybrid chain-like zincoborate [Zn(dap)3][Zn(dap)B5O8(OH)2]2 (1, dap = 1,2-diaminopropane) has been made under solvothermal conditions. The structure was determined by single crystal X-ray diffraction and further characterized by elemental analysis, FT-IR, thermogravimetric analysis and photo-luminescence spectroscopy. Crystal data for 1: orthorhombic, Pca21 (No. 29), a = 12.5696(4) Å, b = 12.9506(6) Å, c = 25.2370(10) Å, Z = 4. The structure of 1 features one-dimensional (1-D) inorganic–organic hybrid zincoborate helical chain, which was constructed from the assembly of [B5O8(OH)2]3− clusters and Zn(dap) linkers. Adjacent zincoborate chains are further linked by [Zn(dap)3] complexes through extensive hydrogen-bonds to generate 3-D supramolecular network. Two distinct coordination-modes of zinc centers are simultaneously observed in the structure, and they play different roles in the formation of the resultant framework. In addition, 1 exhibits extensive luminescence and moderate second-harmonic generation efficiency.
AB - A new organic–inorganic hybrid chain-like zincoborate [Zn(dap)3][Zn(dap)B5O8(OH)2]2 (1, dap = 1,2-diaminopropane) has been made under solvothermal conditions. The structure was determined by single crystal X-ray diffraction and further characterized by elemental analysis, FT-IR, thermogravimetric analysis and photo-luminescence spectroscopy. Crystal data for 1: orthorhombic, Pca21 (No. 29), a = 12.5696(4) Å, b = 12.9506(6) Å, c = 25.2370(10) Å, Z = 4. The structure of 1 features one-dimensional (1-D) inorganic–organic hybrid zincoborate helical chain, which was constructed from the assembly of [B5O8(OH)2]3− clusters and Zn(dap) linkers. Adjacent zincoborate chains are further linked by [Zn(dap)3] complexes through extensive hydrogen-bonds to generate 3-D supramolecular network. Two distinct coordination-modes of zinc centers are simultaneously observed in the structure, and they play different roles in the formation of the resultant framework. In addition, 1 exhibits extensive luminescence and moderate second-harmonic generation efficiency.
KW - Borate cluster
KW - Crystal structure
KW - Hybrid structure
KW - Transition-metal complexes
KW - Zincoborate
UR - http://www.scopus.com/inward/record.url?scp=85007452818&partnerID=8YFLogxK
U2 - 10.1007/s10876-016-1149-x
DO - 10.1007/s10876-016-1149-x
M3 - Article
AN - SCOPUS:85007452818
SN - 1040-7278
VL - 28
SP - 1421
EP - 1429
JO - Journal of Cluster Science
JF - Journal of Cluster Science
IS - 3
ER -