Visible-Light-Driven, Palladium-Catalyzed Heck Reaction of Internal Vinyl Bromides with Styrenes

Yunlong Li; Haibo Liu; Zilong Huang; Yuan He; Bao Hua Xu; Hongmei Wang; Zhengkun Yu

doi:10.1021/acs.joc.1c00838

Visible-Light-Driven, Palladium-Catalyzed Heck Reaction of Internal Vinyl Bromides with Styrenes

Yunlong Li, Haibo Liu, Zilong Huang, Yuan He, Bao Hua Xu, Hongmei Wang^*, Zhengkun Yu^*

^*此作品的通讯作者

科研成果: 期刊稿件 › 文章 › 同行评审

4 引用（Scopus）

摘要

Functionalized 1,3-dienes were efficiently accessed from visible-light-driven, palladium-catalyzed Heck reaction of S,S-functionalized internal vinyl bromides with styrenes under mild conditions. This Heck reaction showcased tolerance of a wide array of functional groups, afforded the target products in moderate to excellent yields through a radical reaction pathway. The resultant diene products could be further transformed to highly functionalized trisubstituted furan derivatives.

源语言	英语
页（从-至）	8402-8413
页数	12
期刊	Journal of Organic Chemistry
卷	86
期	12
DOI	https://doi.org/10.1021/acs.joc.1c00838
出版状态	已出版 - 18 6月 2021
已对外发布	是

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abstract = "Functionalized 1,3-dienes were efficiently accessed from visible-light-driven, palladium-catalyzed Heck reaction of S,S-functionalized internal vinyl bromides with styrenes under mild conditions. This Heck reaction showcased tolerance of a wide array of functional groups, afforded the target products in moderate to excellent yields through a radical reaction pathway. The resultant diene products could be further transformed to highly functionalized trisubstituted furan derivatives.",

author = "Yunlong Li and Haibo Liu and Zilong Huang and Yuan He and Xu, {Bao Hua} and Hongmei Wang and Zhengkun Yu",

note = "Publisher Copyright: {\textcopyright} 2021 American Chemical Society.",

year = "2021",

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AU - Li, Yunlong

AU - Liu, Haibo

AU - Huang, Zilong

AU - He, Yuan

AU - Xu, Bao Hua

AU - Wang, Hongmei

AU - Yu, Zhengkun

PY - 2021/6/18

Y1 - 2021/6/18

N2 - Functionalized 1,3-dienes were efficiently accessed from visible-light-driven, palladium-catalyzed Heck reaction of S,S-functionalized internal vinyl bromides with styrenes under mild conditions. This Heck reaction showcased tolerance of a wide array of functional groups, afforded the target products in moderate to excellent yields through a radical reaction pathway. The resultant diene products could be further transformed to highly functionalized trisubstituted furan derivatives.

AB - Functionalized 1,3-dienes were efficiently accessed from visible-light-driven, palladium-catalyzed Heck reaction of S,S-functionalized internal vinyl bromides with styrenes under mild conditions. This Heck reaction showcased tolerance of a wide array of functional groups, afforded the target products in moderate to excellent yields through a radical reaction pathway. The resultant diene products could be further transformed to highly functionalized trisubstituted furan derivatives.

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IS - 12

ER -

Visible-Light-Driven, Palladium-Catalyzed Heck Reaction of Internal Vinyl Bromides with Styrenes

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