vic-difluorination of fluoroalkenes with xenon difiuoride: The effect of fluorine substituents on the reaction of alkenes with xenon difluoride

Masanori Tamura*, Heng Dao Quan, Akira Sekiya

*此作品的通讯作者

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6 引用 (Scopus)

摘要

vic-Difluorination proceeds by the reaction of fluoroalkenes with xenon difluoride to afford the corresponding fluorinated compounds. From the reaction with polyfluoroalkenes, the products are obtained in high to excellent yields. In this reaction, the fluorine atom substituent of alkene stabilizes the cation intermediate and suppresses side-reactions such as rearrangement.

源语言英语
页(从-至)3151-3153
页数3
期刊European Journal of Organic Chemistry
11
DOI
出版状态已出版 - 11月 1999
已对外发布

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