Unusual behaviour of a new kind of side chain crown ether polysiloxanes used in capillary gas chromatography

Peng Jing, Ruonong Fu*, Wei Zhou, Rongji Dai, Zaifu Huang, Yanfei Chen

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摘要

A new side chain crown ether polysiloxane (PSCP-3-15C5) has been prepared and characterized in chromatography. Its chromatographic behaviour was compared with that of the other side chain crown ether polysiloxane (PSCP-11-15-C5), which has a longer spacer. The unusual effects caused by the length of the spacer on the polysiloxane backbone are described. An interesting phenomenon, liquid-liquid transition occurring in the measurement of phase transition on PSCP-3-15-C5, is discussed.

源语言英语
页(从-至)189-195
页数7
期刊Journal of Chromatography A
752
1-2
DOI
出版状态已出版 - 1 11月 1996

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Jing, P., Fu, R., Zhou, W., Dai, R., Huang, Z., & Chen, Y. (1996). Unusual behaviour of a new kind of side chain crown ether polysiloxanes used in capillary gas chromatography. Journal of Chromatography A, 752(1-2), 189-195. https://doi.org/10.1016/S0021-9673(96)00479-7