Unprecedented 3D polycatenation based on ribbons of rings found in two metallosupramolecular polymers whose open frameworks show reversible collapse upon de- and rehydration

Qing Xia Yao; Zhan Feng Ju; Wei Li; Wei Wu; Shou Tian Zheng; Jie Zhang

doi:10.1039/b810523p

Unprecedented 3D polycatenation based on ribbons of rings found in two metallosupramolecular polymers whose open frameworks show reversible collapse upon de- and rehydration

Qing Xia Yao, Zhan Feng Ju, Wei Li, Wei Wu, Shou Tian Zheng, Jie Zhang^*

^*此作品的通讯作者

CAS - Fujian Institute of Research on the Structure of Matter

科研成果: 期刊稿件 › 文章 › 同行评审

30 引用（Scopus）

摘要

Two isostructural metallosupramolecular polymers [M(H₂O) ₄-(BCbpy)₂]₂Cl₄·18H ₂O [M = Co(ii), Ni(ii); HBCbpyCl = 1-(4-carboxybenzyl)-4,4′- bipyridinium chloride] have been synthesized by the self-assembly reaction of HBCbpyCl salt with MCl₂ (M = Co, Ni). The unprecedented catenation of the (1D → 3D) type based on ribbons of rings is found in both supramolecular networks. Interestingly, this catenation mode can help generate channels, and the resulting supramolecular frameworks show recoverable collapse upon de- and rehydration, making them good potential adsorbents of water vapor.

源语言	英语
页（从-至）	1299-1301
页数	3
期刊	CrystEngComm
卷	10
期	10
DOI	https://doi.org/10.1039/b810523p
出版状态	已出版 - 2008
已对外发布	是

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Yao, Q. X., Ju, Z. F., Li, W., Wu, W., Zheng, S. T., & Zhang, J. (2008). Unprecedented 3D polycatenation based on ribbons of rings found in two metallosupramolecular polymers whose open frameworks show reversible collapse upon de- and rehydration. CrystEngComm, 10(10), 1299-1301. https://doi.org/10.1039/b810523p

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abstract = "Two isostructural metallosupramolecular polymers [M(H2O) 4-(BCbpy)2]2Cl4·18H 2O [M = Co(ii), Ni(ii); HBCbpyCl = 1-(4-carboxybenzyl)-4,4′- bipyridinium chloride] have been synthesized by the self-assembly reaction of HBCbpyCl salt with MCl2 (M = Co, Ni). The unprecedented catenation of the (1D → 3D) type based on ribbons of rings is found in both supramolecular networks. Interestingly, this catenation mode can help generate channels, and the resulting supramolecular frameworks show recoverable collapse upon de- and rehydration, making them good potential adsorbents of water vapor.",

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AU - Li, Wei

AU - Wu, Wei

AU - Zheng, Shou Tian

AU - Zhang, Jie

PY - 2008

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AB - Two isostructural metallosupramolecular polymers [M(H2O) 4-(BCbpy)2]2Cl4·18H 2O [M = Co(ii), Ni(ii); HBCbpyCl = 1-(4-carboxybenzyl)-4,4′- bipyridinium chloride] have been synthesized by the self-assembly reaction of HBCbpyCl salt with MCl2 (M = Co, Ni). The unprecedented catenation of the (1D → 3D) type based on ribbons of rings is found in both supramolecular networks. Interestingly, this catenation mode can help generate channels, and the resulting supramolecular frameworks show recoverable collapse upon de- and rehydration, making them good potential adsorbents of water vapor.

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Unprecedented 3D polycatenation based on ribbons of rings found in two metallosupramolecular polymers whose open frameworks show reversible collapse upon de- and rehydration

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