Unlocking Inter- to Non-Penetrating Frameworks Using Steric Influences on Spacers for CO2 Adsorption

Sheng Li Huang, Wen Hua Zhang, Yun Ling, Seik Weng Ng, He Kuan Luo*, T. S.Andy Hor

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

10 引用 (Scopus)

摘要

Four porous coordination networks have been synthesized from 1,4-benzenedicarboxylate with Cl, Br, I, and NO2 substituents whose different spatial differences are sufficient to influence the coordination mode of adjacent carboxyl moieties to unlock an inter-penetrating framework to give isostructural structures. Their size and polarity differences account for the diverging CO2 adsorption performances.

源语言英语
页(从-至)2117-2120
页数4
期刊Chemistry - An Asian Journal
10
10
DOI
出版状态已出版 - 1 10月 2015
已对外发布

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