Understanding the charge transport and polarities in organic donor-acceptor mixed-stack crystals: Molecular insights from the super-exchange couplings

Hua Geng, Xiaoyan Zheng, Zhigang Shuai*, Lingyun Zhu, Yuanping Yi

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

103 引用 (Scopus)

摘要

Charge transport and polarity, in organic D-A mixed-stack crystals are examined in terms of super-exchange electronic couplings. When the super-exchange coupling is dominated by the interaction between donor HOMO and acceptor LUMO, ambipolar transport is achieved. Otherwise, involvement of other bridge orbitals can lead to unbalanced, even to unipolar transport in a special case that the HOMO-LUMO interaction vanishes.

源语言英语
页(从-至)1443-1449
页数7
期刊Advanced Materials
27
8
DOI
出版状态已出版 - 25 2月 2015
已对外发布

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