Two inorganic-organic hybrid polyoxotungstates constructed from tetra-ZrIV-substituted sandwich-type germanotungstates functionalized by tris ligand

Zhong Zhang; Yue Lin Wang; Guo Yu Yang

doi:10.1016/j.inoche.2017.05.019

Two inorganic-organic hybrid polyoxotungstates constructed from tetra-Zr^IV-substituted sandwich-type germanotungstates functionalized by tris ligand

Zhong Zhang, Yue Lin Wang, Guo Yu Yang^*

^*此作品的通讯作者

化学与化工学院

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

11 引用（Scopus）

摘要

Two tris-functionalized Zr₄^IV-substituted germanetungstates H₉KNa₂[Zr₄(μ₃-O)₂(tris)₂(α-GeW₁₀O₃₇)₂]·26H₂O (1) and H₂K₆Na₄[Zr₄(μ₃-O)₂(tris)₂(α-GeW₁₀O₃₇)₂]·20H₂O (2) (tris = tris(hydroxymethyl)aminomethane) have been made under mild hydrothermal conditions and characterized by elemental analysis, IR spectra, diffuse reflectance spectra, thermogravimetric analysis, single-crystal X-ray diffraction and powder X-ray diffraction, respectively. 1–2 possess similar sandwich-type polyoxoanion structure built by a tetra-Zr^IV cluster and two divacant [α-GeW₁₀O₃₇]^{10 −} building blocks. 1 and 2 represent the first [Zr₄(μ₃-O)₂(tris)₂]¹⁰⁺-substituted germanotungstates functionalized by tris ligands with O– and N-donors.

源语言	英语
页（从-至）	32-36
页数	5
期刊	Inorganic Chemistry Communications
卷	85
DOI	https://doi.org/10.1016/j.inoche.2017.05.019
出版状态	已出版 - 11月 2017

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@article{3f03accbc20647dabbdc1cc80de49ff2,

title = "Two inorganic-organic hybrid polyoxotungstates constructed from tetra-ZrIV-substituted sandwich-type germanotungstates functionalized by tris ligand",

abstract = "Two tris-functionalized Zr4IV-substituted germanetungstates H9KNa2[Zr4(μ3-O)2(tris)2(α-GeW10O37)2]·26H2O (1) and H2K6Na4[Zr4(μ3-O)2(tris)2(α-GeW10O37)2]·20H2O (2) (tris = tris(hydroxymethyl)aminomethane) have been made under mild hydrothermal conditions and characterized by elemental analysis, IR spectra, diffuse reflectance spectra, thermogravimetric analysis, single-crystal X-ray diffraction and powder X-ray diffraction, respectively. 1–2 possess similar sandwich-type polyoxoanion structure built by a tetra-ZrIV cluster and two divacant [α-GeW10O37]10 − building blocks. 1 and 2 represent the first [Zr4(μ3-O)2(tris)2]10+-substituted germanotungstates functionalized by tris ligands with O– and N-donors.",

keywords = "Hydrothermal synthesis, Polyoxometalate, Tris-functionalized, Zirconium(IV)-substituted cluster",

author = "Zhong Zhang and Wang, {Yue Lin} and Yang, {Guo Yu}",

note = "Publisher Copyright: {\textcopyright} 2017",

year = "2017",

month = nov,

doi = "10.1016/j.inoche.2017.05.019",

language = "English",

volume = "85",

pages = "32--36",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Two inorganic-organic hybrid polyoxotungstates constructed from tetra-ZrIV-substituted sandwich-type germanotungstates functionalized by tris ligand

AU - Zhang, Zhong

AU - Wang, Yue Lin

AU - Yang, Guo Yu

PY - 2017/11

Y1 - 2017/11

N2 - Two tris-functionalized Zr4IV-substituted germanetungstates H9KNa2[Zr4(μ3-O)2(tris)2(α-GeW10O37)2]·26H2O (1) and H2K6Na4[Zr4(μ3-O)2(tris)2(α-GeW10O37)2]·20H2O (2) (tris = tris(hydroxymethyl)aminomethane) have been made under mild hydrothermal conditions and characterized by elemental analysis, IR spectra, diffuse reflectance spectra, thermogravimetric analysis, single-crystal X-ray diffraction and powder X-ray diffraction, respectively. 1–2 possess similar sandwich-type polyoxoanion structure built by a tetra-ZrIV cluster and two divacant [α-GeW10O37]10 − building blocks. 1 and 2 represent the first [Zr4(μ3-O)2(tris)2]10+-substituted germanotungstates functionalized by tris ligands with O– and N-donors.

AB - Two tris-functionalized Zr4IV-substituted germanetungstates H9KNa2[Zr4(μ3-O)2(tris)2(α-GeW10O37)2]·26H2O (1) and H2K6Na4[Zr4(μ3-O)2(tris)2(α-GeW10O37)2]·20H2O (2) (tris = tris(hydroxymethyl)aminomethane) have been made under mild hydrothermal conditions and characterized by elemental analysis, IR spectra, diffuse reflectance spectra, thermogravimetric analysis, single-crystal X-ray diffraction and powder X-ray diffraction, respectively. 1–2 possess similar sandwich-type polyoxoanion structure built by a tetra-ZrIV cluster and two divacant [α-GeW10O37]10 − building blocks. 1 and 2 represent the first [Zr4(μ3-O)2(tris)2]10+-substituted germanotungstates functionalized by tris ligands with O– and N-donors.

KW - Hydrothermal synthesis

KW - Polyoxometalate

KW - Tris-functionalized

KW - Zirconium(IV)-substituted cluster

UR - http://www.scopus.com/inward/record.url?scp=85019760593&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2017.05.019

DO - 10.1016/j.inoche.2017.05.019

M3 - Article

AN - SCOPUS:85019760593

SN - 1387-7003

VL - 85

SP - 32

EP - 36

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Two inorganic-organic hybrid polyoxotungstates constructed from tetra-ZrIV-substituted sandwich-type germanotungstates functionalized by tris ligand

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Two inorganic-organic hybrid polyoxotungstates constructed from tetra-Zr^IV-substituted sandwich-type germanotungstates functionalized by tris ligand