Two chiral multinuclear palladium(ii) complexes comprising alternately arranged isomerous hexanuclear clusters

Zhengguo Lin; Baokuan Chen; Xiao Feng; Bo Wang; Yingnan Chi; Yanxuan Fan; Xinhang Yang; Xianqiang Huang; Changwen Hu

doi:10.1039/c3ce40773j

Two chiral multinuclear palladium(ii) complexes comprising alternately arranged isomerous hexanuclear clusters

Zhengguo Lin, Baokuan Chen, Xiao Feng, Bo Wang^*, Yingnan Chi, Yanxuan Fan, Xinhang Yang, Xianqiang Huang, Changwen Hu

^*此作品的通讯作者

化学与化工学院

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

7 引用（Scopus）

摘要

Two new chiral hexanuclear palladium(ii) complexes [Pd₆(Cys) ₄(CysH)₄][Pd₆(CysH)₈]Cl ₄·24H₂O (1) and [Pd₆(HCys) ₁₀](NO₃)₂·11H₂O (2) are prepared through careful control of the reaction conditions. Both complexes comprise two alternately arranged isomerous hexanuclear Pd(ii) clusters. As supported by ESI-MS spectra and CD analyses, the integrity of the structures can be maintained in aqueous solution and the chirality of l-Cys ligands can be preserved to the multinuclear Pd complexes.

源语言	英语
页（从-至）	6461-6464
页数	4
期刊	CrystEngComm
卷	15
期	33
DOI	https://doi.org/10.1039/c3ce40773j
出版状态	已出版 - 7 9月 2013

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title = "Two chiral multinuclear palladium(ii) complexes comprising alternately arranged isomerous hexanuclear clusters",

abstract = "Two new chiral hexanuclear palladium(ii) complexes [Pd6(Cys) 4(CysH)4][Pd6(CysH)8]Cl 4·24H2O (1) and [Pd6(HCys) 10](NO3)2·11H2O (2) are prepared through careful control of the reaction conditions. Both complexes comprise two alternately arranged isomerous hexanuclear Pd(ii) clusters. As supported by ESI-MS spectra and CD analyses, the integrity of the structures can be maintained in aqueous solution and the chirality of l-Cys ligands can be preserved to the multinuclear Pd complexes.",

author = "Zhengguo Lin and Baokuan Chen and Xiao Feng and Bo Wang and Yingnan Chi and Yanxuan Fan and Xinhang Yang and Xianqiang Huang and Changwen Hu",

year = "2013",

month = sep,

day = "7",

doi = "10.1039/c3ce40773j",

language = "English",

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T1 - Two chiral multinuclear palladium(ii) complexes comprising alternately arranged isomerous hexanuclear clusters

AU - Lin, Zhengguo

AU - Chen, Baokuan

AU - Feng, Xiao

AU - Wang, Bo

AU - Chi, Yingnan

AU - Fan, Yanxuan

AU - Yang, Xinhang

AU - Huang, Xianqiang

AU - Hu, Changwen

PY - 2013/9/7

Y1 - 2013/9/7

N2 - Two new chiral hexanuclear palladium(ii) complexes [Pd6(Cys) 4(CysH)4][Pd6(CysH)8]Cl 4·24H2O (1) and [Pd6(HCys) 10](NO3)2·11H2O (2) are prepared through careful control of the reaction conditions. Both complexes comprise two alternately arranged isomerous hexanuclear Pd(ii) clusters. As supported by ESI-MS spectra and CD analyses, the integrity of the structures can be maintained in aqueous solution and the chirality of l-Cys ligands can be preserved to the multinuclear Pd complexes.

AB - Two new chiral hexanuclear palladium(ii) complexes [Pd6(Cys) 4(CysH)4][Pd6(CysH)8]Cl 4·24H2O (1) and [Pd6(HCys) 10](NO3)2·11H2O (2) are prepared through careful control of the reaction conditions. Both complexes comprise two alternately arranged isomerous hexanuclear Pd(ii) clusters. As supported by ESI-MS spectra and CD analyses, the integrity of the structures can be maintained in aqueous solution and the chirality of l-Cys ligands can be preserved to the multinuclear Pd complexes.

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DO - 10.1039/c3ce40773j

M3 - Article

AN - SCOPUS:84881109530

SN - 1466-8033

VL - 15

SP - 6461

EP - 6464

JO - CrystEngComm

JF - CrystEngComm

IS - 33

ER -

Two chiral multinuclear palladium(ii) complexes comprising alternately arranged isomerous hexanuclear clusters

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