TY - JOUR
T1 - Tris(2,2'-bipyridine)nickel(II) diperchlorate
AU - Zhou, Youfu
AU - Li, Xing
AU - Xu, Yanqing
AU - Cao, Rong
AU - Hong, Maochun
PY - 2003/5
Y1 - 2003/5
N2 - The title compound, [Ni(C10H8N2) 3](ClO4)2, is built up of monomeric [Ni(bpy)3]2+ cations (bpy = 2,2'-bipyridine) and two perchlorate anions. The asymmetric unit is one half cation and one anion, a twofold rotation axis passing through the Ni atom and bisecting one bpy ligand. The NiII ion is coordinated by six N atoms from three chelating bpy ligands in a highly distorted octahedral geometry, with Ni-N bond lengths ranging from 2.071 (4) to 2.091 (4) Å.
AB - The title compound, [Ni(C10H8N2) 3](ClO4)2, is built up of monomeric [Ni(bpy)3]2+ cations (bpy = 2,2'-bipyridine) and two perchlorate anions. The asymmetric unit is one half cation and one anion, a twofold rotation axis passing through the Ni atom and bisecting one bpy ligand. The NiII ion is coordinated by six N atoms from three chelating bpy ligands in a highly distorted octahedral geometry, with Ni-N bond lengths ranging from 2.071 (4) to 2.091 (4) Å.
UR - http://www.scopus.com/inward/record.url?scp=18444379957&partnerID=8YFLogxK
U2 - 10.1107/S1600536803008778
DO - 10.1107/S1600536803008778
M3 - Article
AN - SCOPUS:18444379957
SN - 1600-5368
VL - 59
SP - m300-m302
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 5
ER -