Three hydrogen-bonded nanotubular zinc(II) complexes of N-(9-anthracenyl)-N'-(4-pyridyl)-urea

Qilong Zhao; Xiao Juan Yang; Chuandong Jia; Biao Wu

doi:10.1016/j.inoche.2010.04.018

Three hydrogen-bonded nanotubular zinc(II) complexes of N-(9-anthracenyl)-N'-(4-pyridyl)-urea

Qilong Zhao, Xiao Juan Yang^*, Chuandong Jia, Biao Wu

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摘要

Three hydrogen-bonded nanotubular zinc(II) complexes of a monodentate ligand N-(9-anthracenyl)-N'-(4- pyridyl)urea (L), [Zn(OAc)₂L ₂]•H₂O (1), [ZnBr(OAc)L₂]•H ₂O (2) and [ZnCl(OAc)L₂]•4H₂O (3), were synthesized and structurally characterized. In the complexes, the central metal ion is tetrahedrally coordinated by the pyridyl nitrogen atoms of two ligands and different anions, while the urea groups of the ligands self-associate into the typical urea tape through R2/1 (6) hydrogen bonds, which are essential for the formation of the nanotubes. The fluorescence properties of ligand L and the complexes were studied in the solid state at room temperature.

源语言	英语
页（从-至）	873-877
页数	5
期刊	Inorganic Chemistry Communications
卷	13
期	7
DOI	https://doi.org/10.1016/j.inoche.2010.04.018
出版状态	已出版 - 7月 2010
已对外发布	是

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Zhao, Q., Yang, X. J., Jia, C., & Wu, B. (2010). Three hydrogen-bonded nanotubular zinc(II) complexes of N-(9-anthracenyl)-N'-(4-pyridyl)-urea. Inorganic Chemistry Communications, 13(7), 873-877. https://doi.org/10.1016/j.inoche.2010.04.018

@article{36161e8974b9433c81b1114fa53a4f42,

title = "Three hydrogen-bonded nanotubular zinc(II) complexes of N-(9-anthracenyl)-N'-(4-pyridyl)-urea",

abstract = "Three hydrogen-bonded nanotubular zinc(II) complexes of a monodentate ligand N-(9-anthracenyl)-N'-(4- pyridyl)urea (L), [Zn(OAc)2L 2]•H2O (1), [ZnBr(OAc)L2]•H 2O (2) and [ZnCl(OAc)L2]•4H2O (3), were synthesized and structurally characterized. In the complexes, the central metal ion is tetrahedrally coordinated by the pyridyl nitrogen atoms of two ligands and different anions, while the urea groups of the ligands self-associate into the typical urea tape through R2/1 (6) hydrogen bonds, which are essential for the formation of the nanotubes. The fluorescence properties of ligand L and the complexes were studied in the solid state at room temperature.",

keywords = "Fluorescence, Hydrogen-bonded nanotubes, Monodentate, Pyridylurea",

author = "Qilong Zhao and Yang, {Xiao Juan} and Chuandong Jia and Biao Wu",

year = "2010",

month = jul,

doi = "10.1016/j.inoche.2010.04.018",

language = "English",

volume = "13",

pages = "873--877",

journal = "Inorganic Chemistry Communications",

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TY - JOUR

T1 - Three hydrogen-bonded nanotubular zinc(II) complexes of N-(9-anthracenyl)-N'-(4-pyridyl)-urea

AU - Zhao, Qilong

AU - Yang, Xiao Juan

AU - Jia, Chuandong

AU - Wu, Biao

PY - 2010/7

Y1 - 2010/7

N2 - Three hydrogen-bonded nanotubular zinc(II) complexes of a monodentate ligand N-(9-anthracenyl)-N'-(4- pyridyl)urea (L), [Zn(OAc)2L 2]•H2O (1), [ZnBr(OAc)L2]•H 2O (2) and [ZnCl(OAc)L2]•4H2O (3), were synthesized and structurally characterized. In the complexes, the central metal ion is tetrahedrally coordinated by the pyridyl nitrogen atoms of two ligands and different anions, while the urea groups of the ligands self-associate into the typical urea tape through R2/1 (6) hydrogen bonds, which are essential for the formation of the nanotubes. The fluorescence properties of ligand L and the complexes were studied in the solid state at room temperature.

AB - Three hydrogen-bonded nanotubular zinc(II) complexes of a monodentate ligand N-(9-anthracenyl)-N'-(4- pyridyl)urea (L), [Zn(OAc)2L 2]•H2O (1), [ZnBr(OAc)L2]•H 2O (2) and [ZnCl(OAc)L2]•4H2O (3), were synthesized and structurally characterized. In the complexes, the central metal ion is tetrahedrally coordinated by the pyridyl nitrogen atoms of two ligands and different anions, while the urea groups of the ligands self-associate into the typical urea tape through R2/1 (6) hydrogen bonds, which are essential for the formation of the nanotubes. The fluorescence properties of ligand L and the complexes were studied in the solid state at room temperature.

KW - Fluorescence

KW - Hydrogen-bonded nanotubes

KW - Monodentate

KW - Pyridylurea

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U2 - 10.1016/j.inoche.2010.04.018

DO - 10.1016/j.inoche.2010.04.018

M3 - Article

AN - SCOPUS:77954213942

SN - 1387-7003

VL - 13

SP - 873

EP - 877

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 7

ER -

Three hydrogen-bonded nanotubular zinc(II) complexes of N-(9-anthracenyl)-N'-(4-pyridyl)-urea

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