Thermoregulated organic biphasic hydrogenation of 1-octene catalyzed by Ru/PETPP complex

Ya Dong Lu; Yan Hua Wang; Zi Lin Jin

Thermoregulated organic biphasic hydrogenation of 1-octene catalyzed by Ru/PETPP complex

Ya Dong Lu^*, Yan Hua Wang, Zi Lin Jin

^*此作品的通讯作者

Dalian University of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

摘要

Thermoregulated organic biphasic system composed of triethylene glycol monomethyl ether (TGME) and n-heptane was first applied to the hydrogenation of 1-octene. Under the optimal conditions: P(H₂)=5.0MPa, T=80°C, t=3h, 1-octene/Ru=1000 (molar ratio), the yield of n-octane reached up to 99.6%. Furthermore, the simply decanted catalyst could be reused for 10 times without apparent loss of catalytic activity.

源语言	英语
页（从-至）	255-257
页数	3
期刊	Chinese Chemical Letters
卷	17
期	2
出版状态	已出版 - 2月 2006
已对外发布	是

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title = "Thermoregulated organic biphasic hydrogenation of 1-octene catalyzed by Ru/PETPP complex",

abstract = "Thermoregulated organic biphasic system composed of triethylene glycol monomethyl ether (TGME) and n-heptane was first applied to the hydrogenation of 1-octene. Under the optimal conditions: P(H2)=5.0MPa, T=80°C, t=3h, 1-octene/Ru=1000 (molar ratio), the yield of n-octane reached up to 99.6%. Furthermore, the simply decanted catalyst could be reused for 10 times without apparent loss of catalytic activity.",

keywords = "1-octene, Hydrogenation, Ruthenium, Thermoregulated organic biphasic system",

author = "Lu, {Ya Dong} and Wang, {Yan Hua} and Jin, {Zi Lin}",

year = "2006",

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AU - Wang, Yan Hua

AU - Jin, Zi Lin

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N2 - Thermoregulated organic biphasic system composed of triethylene glycol monomethyl ether (TGME) and n-heptane was first applied to the hydrogenation of 1-octene. Under the optimal conditions: P(H2)=5.0MPa, T=80°C, t=3h, 1-octene/Ru=1000 (molar ratio), the yield of n-octane reached up to 99.6%. Furthermore, the simply decanted catalyst could be reused for 10 times without apparent loss of catalytic activity.

AB - Thermoregulated organic biphasic system composed of triethylene glycol monomethyl ether (TGME) and n-heptane was first applied to the hydrogenation of 1-octene. Under the optimal conditions: P(H2)=5.0MPa, T=80°C, t=3h, 1-octene/Ru=1000 (molar ratio), the yield of n-octane reached up to 99.6%. Furthermore, the simply decanted catalyst could be reused for 10 times without apparent loss of catalytic activity.

KW - 1-octene

KW - Hydrogenation

KW - Ruthenium

KW - Thermoregulated organic biphasic system

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SN - 1001-8417

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JO - Chinese Chemical Letters

JF - Chinese Chemical Letters

IS - 2

ER -

Thermoregulated organic biphasic hydrogenation of 1-octene catalyzed by Ru/PETPP complex

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