The effects of molecular configuration on the photochromism and decolorization of two bipyridinium-based coordination polymers

Xiao Dong Yang; Cheng Chen; Ya Jun Zhang; Li Xuan Cai; Jie Zhang

doi:10.1016/j.inoche.2015.07.022

The effects of molecular configuration on the photochromism and decolorization of two bipyridinium-based coordination polymers

Xiao Dong Yang, Cheng Chen, Ya Jun Zhang, Li Xuan Cai, Jie Zhang^*

^*此作品的通讯作者

科研成果: 期刊稿件 › 文章 › 同行评审

23 引用（Scopus）

摘要

Two layer-like coordination polymers, {[Cd(Bpyen)_0.5(m-BDC)(H₂O)Br]·4H₂O}(1) and {[Cd(Bpyen)_0.5(o-BDC)Br]·H₂O}(2), have been solvothermally synthesized and structurally characterized. The two compounds own common rapid photochromic response but different decolorization behaviors. The photoproduct of compound 2 is more stable in air. The relationship between structure and photoresponsive behavior has been studied in detail.

源语言	英语
页（从-至）	122-125
页数	4
期刊	Inorganic Chemistry Communications
卷	60
DOI	https://doi.org/10.1016/j.inoche.2015.07.022
出版状态	已出版 - 27 10月 2015
已对外发布	是

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Yang, X. D., Chen, C., Zhang, Y. J., Cai, L. X., & Zhang, J. (2015). The effects of molecular configuration on the photochromism and decolorization of two bipyridinium-based coordination polymers. Inorganic Chemistry Communications, 60, 122-125. https://doi.org/10.1016/j.inoche.2015.07.022

@article{977db6615ef1409eb2a6d4a6329dfeec,

title = "The effects of molecular configuration on the photochromism and decolorization of two bipyridinium-based coordination polymers",

abstract = "Two layer-like coordination polymers, {[Cd(Bpyen)0.5(m-BDC)(H2O)Br]·4H2O}(1) and {[Cd(Bpyen)0.5(o-BDC)Br]·H2O}(2), have been solvothermally synthesized and structurally characterized. The two compounds own common rapid photochromic response but different decolorization behaviors. The photoproduct of compound 2 is more stable in air. The relationship between structure and photoresponsive behavior has been studied in detail.",

keywords = "(6,3) topology, Bipyridinium, Cadmium(II) complex, Decolorization, Photochromism, Single crystal",

author = "Yang, {Xiao Dong} and Cheng Chen and Zhang, {Ya Jun} and Cai, {Li Xuan} and Jie Zhang",

year = "2015",

month = oct,

day = "27",

doi = "10.1016/j.inoche.2015.07.022",

language = "English",

volume = "60",

pages = "122--125",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

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T1 - The effects of molecular configuration on the photochromism and decolorization of two bipyridinium-based coordination polymers

AU - Yang, Xiao Dong

AU - Chen, Cheng

AU - Zhang, Ya Jun

AU - Cai, Li Xuan

AU - Zhang, Jie

PY - 2015/10/27

Y1 - 2015/10/27

N2 - Two layer-like coordination polymers, {[Cd(Bpyen)0.5(m-BDC)(H2O)Br]·4H2O}(1) and {[Cd(Bpyen)0.5(o-BDC)Br]·H2O}(2), have been solvothermally synthesized and structurally characterized. The two compounds own common rapid photochromic response but different decolorization behaviors. The photoproduct of compound 2 is more stable in air. The relationship between structure and photoresponsive behavior has been studied in detail.

AB - Two layer-like coordination polymers, {[Cd(Bpyen)0.5(m-BDC)(H2O)Br]·4H2O}(1) and {[Cd(Bpyen)0.5(o-BDC)Br]·H2O}(2), have been solvothermally synthesized and structurally characterized. The two compounds own common rapid photochromic response but different decolorization behaviors. The photoproduct of compound 2 is more stable in air. The relationship between structure and photoresponsive behavior has been studied in detail.

KW - (6,3) topology

KW - Bipyridinium

KW - Cadmium(II) complex

KW - Decolorization

KW - Photochromism

KW - Single crystal

UR - http://www.scopus.com/inward/record.url?scp=84940039699&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2015.07.022

DO - 10.1016/j.inoche.2015.07.022

M3 - Article

AN - SCOPUS:84940039699

SN - 1387-7003

VL - 60

SP - 122

EP - 125

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

The effects of molecular configuration on the photochromism and decolorization of two bipyridinium-based coordination polymers

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