TY - JOUR
T1 - The development in hydroformylation of higher olefin in liquid/liquid biphase systems
AU - Feng, Cuilan
AU - Wang, Yanhua
AU - Jin, Zilin
PY - 2005/3
Y1 - 2005/3
N2 - The development in hydroformylation of higher olefins in liquid/liquid biphase systems is reviewed, partially based on the authors' research results in recent years. The classical aqueous/organic biphase system is unsuitable for hydroformylation of higher olefins. In order to solve this problem, six kinds of improved methods including thermoregulated phase-transfer catalysis are introduced in detail. In addition, the hydroformylation of higher olefins in nonaqueous liquid/liquid biphase systems, such as fluorous biphasic system, non-aqueous ionic liquid and supercritical fluid is also introduced. Meanwhile, the possibilities of commercial applications of each system have been discussed.
AB - The development in hydroformylation of higher olefins in liquid/liquid biphase systems is reviewed, partially based on the authors' research results in recent years. The classical aqueous/organic biphase system is unsuitable for hydroformylation of higher olefins. In order to solve this problem, six kinds of improved methods including thermoregulated phase-transfer catalysis are introduced in detail. In addition, the hydroformylation of higher olefins in nonaqueous liquid/liquid biphase systems, such as fluorous biphasic system, non-aqueous ionic liquid and supercritical fluid is also introduced. Meanwhile, the possibilities of commercial applications of each system have been discussed.
KW - Aqueoues/organic biphase system
KW - Fluorous biphasic system
KW - Hydroformylation
KW - Non-aqueous ionic liquid
KW - Supercritical fluid
KW - Thermoregulated phase-separable catalysis
KW - Thermoregulated phase-transfer catalysis
UR - http://www.scopus.com/inward/record.url?scp=16244396396&partnerID=8YFLogxK
M3 - Review article
AN - SCOPUS:16244396396
SN - 1005-281X
VL - 17
SP - 209
EP - 216
JO - Progress in Chemistry
JF - Progress in Chemistry
IS - 2
ER -