摘要
By mimicking the scaffolds of oligopyridine-based ligands, triurea and tetraurea receptors have been developed for sulfate binding. The triureas (L1, L2) show stronger binding of sulfate than tetraureas (L3, L4) in DMSO because of their better conformational complementarity with sulfate, while the tetraureas display better "water tolerance" benefiting from the chelate effect and hydrophobic effect.
源语言 | 英语 |
---|---|
页(从-至) | 5612-5615 |
页数 | 4 |
期刊 | Organic Letters |
卷 | 12 |
期 | 24 |
DOI | |
出版状态 | 已出版 - 17 12月 2010 |
已对外发布 | 是 |
指纹
探究 'Tetraureas versus triureas in sulfate binding' 的科研主题。它们共同构成独一无二的指纹。引用此
Jia, C., Wu, B., Li, S., Huang, X., & Yang, X. J. (2010). Tetraureas versus triureas in sulfate binding. Organic Letters, 12(24), 5612-5615. https://doi.org/10.1021/ol102221x