摘要
Energetic compounds with fused tetracyclic backbones were synthesized and fully characterized, and their structures were confirmed by single crystal X-ray diffraction. Changes from nonplanar to planar structures led their densities to increase from 1.800 to 1.856 g cm -3 (298 K). Hydrogen bonds and π-π interactions were analyzed to understand this phenomenon. Energetic evaluations showed that compounds 2 and 3 detonated with performance comparable to TATB. Excellent mechanical sensitivities (IS: >40 J; FS: >360 N) indicate the promise of these furazans as insensitive energetic materials.
| 源语言 | 英语 |
|---|---|
| 页（从-至） | 8034-8037 |
| 页数 | 4 |
| 期刊 | Organic and Biomolecular Chemistry |
| 卷 | 16 |
| 期 | 43 |
| DOI | |
| 出版状态 | 已出版 - 2018 |
| 已对外发布 | 是 |
指纹
探究 'Tetracyclic pyrazine-fused furazans as insensitive energetic materials: Syntheses, structures, and properties' 的科研主题。它们共同构成独一无二的指纹。引用此
Sun, Q., Li, X., Lin, Q., & Lu, M. (2018). Tetracyclic pyrazine-fused furazans as insensitive energetic materials: Syntheses, structures, and properties. Organic and Biomolecular Chemistry, 16(43), 8034-8037. https://doi.org/10.1039/c8ob02155d