Synthesis, structure, and magnetic properties of a novel mixed-bridged heterometal tetranuclear complex [Mn2Ni2(MeOSalen)2(μ1,1-N3)2(N3)2]

Hong Peng Jia; Wei Li; Zhan Feng Ju; Jie Zhang

doi:10.1016/j.inoche.2006.12.009

Synthesis, structure, and magnetic properties of a novel mixed-bridged heterometal tetranuclear complex [Mn₂Ni₂(MeOSalen)₂(μ_1,1-N₃)₂(N₃)₂]

Hong Peng Jia, Wei Li, Zhan Feng Ju, Jie Zhang^*

^*此作品的通讯作者

CAS - Fujian Institute of Research on the Structure of Matter

科研成果: 期刊稿件 › 文章 › 同行评审

46 引用（Scopus）

摘要

The first heterometal tetranuclear complex with alternating azido and phenoxo bridges, [Mn₂Ni₂(MeOSalen)₂(μ_1,1-N₃)₂(N₃)₂] (MeOSalenH₂ = bis(3-methoxy)salicylideneimine), was synthesized and structurally characterized by X-ray crystallography and spectroscopic methods. Magnetic studies suggest there is a ferromagnetic interaction between the μ_1,1-azido-bridged Mn(II) ions with J = +2.11 cm^-1, while the Ni(II) ions are diamagnetic in the tetranuclear system.

源语言	英语
页（从-至）	397-400
页数	4
期刊	Inorganic Chemistry Communications
卷	10
期	4
DOI	https://doi.org/10.1016/j.inoche.2006.12.009
出版状态	已出版 - 4月 2007
已对外发布	是

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@article{b842f51547a944209e1c6c5b7c54a839,

title = "Synthesis, structure, and magnetic properties of a novel mixed-bridged heterometal tetranuclear complex [Mn2Ni2(MeOSalen)2(μ1,1-N3)2(N3)2]",

abstract = "The first heterometal tetranuclear complex with alternating azido and phenoxo bridges, [Mn2Ni2(MeOSalen)2(μ1,1-N3)2(N3)2] (MeOSalenH2 = bis(3-methoxy)salicylideneimine), was synthesized and structurally characterized by X-ray crystallography and spectroscopic methods. Magnetic studies suggest there is a ferromagnetic interaction between the μ1,1-azido-bridged Mn(II) ions with J = +2.11 cm-1, while the Ni(II) ions are diamagnetic in the tetranuclear system.",

keywords = "Crystal structure, Heterometallic complex, Magnetic properties, Manganese(II), Nickel(II), Schiff-base",

author = "Jia, {Hong Peng} and Wei Li and Ju, {Zhan Feng} and Jie Zhang",

year = "2007",

month = apr,

doi = "10.1016/j.inoche.2006.12.009",

language = "English",

volume = "10",

pages = "397--400",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "4",

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TY - JOUR

T1 - Synthesis, structure, and magnetic properties of a novel mixed-bridged heterometal tetranuclear complex [Mn2Ni2(MeOSalen)2(μ1,1-N3)2(N3)2]

AU - Jia, Hong Peng

AU - Li, Wei

AU - Ju, Zhan Feng

AU - Zhang, Jie

PY - 2007/4

Y1 - 2007/4

N2 - The first heterometal tetranuclear complex with alternating azido and phenoxo bridges, [Mn2Ni2(MeOSalen)2(μ1,1-N3)2(N3)2] (MeOSalenH2 = bis(3-methoxy)salicylideneimine), was synthesized and structurally characterized by X-ray crystallography and spectroscopic methods. Magnetic studies suggest there is a ferromagnetic interaction between the μ1,1-azido-bridged Mn(II) ions with J = +2.11 cm-1, while the Ni(II) ions are diamagnetic in the tetranuclear system.

AB - The first heterometal tetranuclear complex with alternating azido and phenoxo bridges, [Mn2Ni2(MeOSalen)2(μ1,1-N3)2(N3)2] (MeOSalenH2 = bis(3-methoxy)salicylideneimine), was synthesized and structurally characterized by X-ray crystallography and spectroscopic methods. Magnetic studies suggest there is a ferromagnetic interaction between the μ1,1-azido-bridged Mn(II) ions with J = +2.11 cm-1, while the Ni(II) ions are diamagnetic in the tetranuclear system.

KW - Crystal structure

KW - Heterometallic complex

KW - Magnetic properties

KW - Manganese(II)

KW - Nickel(II)

KW - Schiff-base

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U2 - 10.1016/j.inoche.2006.12.009

DO - 10.1016/j.inoche.2006.12.009

M3 - Article

AN - SCOPUS:33847329571

SN - 1387-7003

VL - 10

SP - 397

EP - 400

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 4

ER -

Synthesis, structure, and magnetic properties of a novel mixed-bridged heterometal tetranuclear complex [Mn2Ni2(MeOSalen)2(μ1,1-N3)2(N3)2]

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Synthesis, structure, and magnetic properties of a novel mixed-bridged heterometal tetranuclear complex [Mn₂Ni₂(MeOSalen)₂(μ_1,1-N₃)₂(N₃)₂]