TY - JOUR
T1 - Synthesis, Structure, and Energetic Properties of 1,5-Diaminotetrazolium Sulfate Salts
AU - Qian, Yao
AU - Han, Zhiyue
AU - Zhang, Yinghao
AU - Du, Zhiming
AU - Zhao, Yan
AU - Yang, Yuezhen
AU - Zhang, Jingchang
N1 - Publisher Copyright:
© 2015 Hetero Corporation.
PY - 2016/3/1
Y1 - 2016/3/1
N2 - 1,5-diaminotetrazolium chloride (DATC) and 1,5-diaminotetrazolium sulfate (DATS) were synthesized in this work. The structures of DATS and DATC were characterized. The single crystal of DATS was first cultured, and its structure was analyzed. The thermal behavior of DATS was investigated. The activation energy and pro-exponential factor were calculated, Ek = 120.86 KJ/mol, Ak = 1012.96 s-1. The density, heat of formation, detonation pressure, and detonation velocity of DATS were first calculated. The detonation pressure and detonation velocity of DATS are P = 11.877 GPa, D = 5.617 km s-1, which are smaller than those of 1,5-diaminotetrazolium nitrate (DATN) (P = 33.3GPa, D = 8.77 km s-1).
AB - 1,5-diaminotetrazolium chloride (DATC) and 1,5-diaminotetrazolium sulfate (DATS) were synthesized in this work. The structures of DATS and DATC were characterized. The single crystal of DATS was first cultured, and its structure was analyzed. The thermal behavior of DATS was investigated. The activation energy and pro-exponential factor were calculated, Ek = 120.86 KJ/mol, Ak = 1012.96 s-1. The density, heat of formation, detonation pressure, and detonation velocity of DATS were first calculated. The detonation pressure and detonation velocity of DATS are P = 11.877 GPa, D = 5.617 km s-1, which are smaller than those of 1,5-diaminotetrazolium nitrate (DATN) (P = 33.3GPa, D = 8.77 km s-1).
UR - http://www.scopus.com/inward/record.url?scp=84952700569&partnerID=8YFLogxK
U2 - 10.1002/jhet.2579
DO - 10.1002/jhet.2579
M3 - Article
AN - SCOPUS:84952700569
SN - 0022-152X
VL - 53
SP - 651
EP - 657
JO - Journal of Heterocyclic Chemistry
JF - Journal of Heterocyclic Chemistry
IS - 2
ER -