TY - JOUR
T1 - Synthesis, structure and characterization of a new nonlinear optical calcium borate [Ca2B5O9]·[H(OH)2]
AU - Sun, Yu Jia
AU - Zhang, Zhong
AU - Wang, Yue Lin
AU - Yang, Guo Yu
N1 - Publisher Copyright:
© 2017
PY - 2017/12
Y1 - 2017/12
N2 - A new nonlinear optical crystal [Ca2B5O9]·[H(OH)2] (1) has been synthesized under hydrothermal condition. Compound 1 crystallizes in the monoclinic space group C2 with lattice constants a = 10.111(2) Å, b = 7.754(11) Å, c = 6.198(14) Å, β = 127.04(3)° and Z = 2. The fundamental building block (FBB) of 1 is a [B5O12] unit with two BO3 triangles and three BO4 tetrahedra. 1 was characterized by single-crystal X-ray diffraction, IR and UV–Vis spectroscopy, thermogravimetric analysis (TGA), powder X-ray diffraction (PXRD) respectively. Also, powder second harmonic generation (SHG) measurements indicate that 1 is phase matchable and displays a SHG response of about 3.5 times that of KDP (KH2PO4).
AB - A new nonlinear optical crystal [Ca2B5O9]·[H(OH)2] (1) has been synthesized under hydrothermal condition. Compound 1 crystallizes in the monoclinic space group C2 with lattice constants a = 10.111(2) Å, b = 7.754(11) Å, c = 6.198(14) Å, β = 127.04(3)° and Z = 2. The fundamental building block (FBB) of 1 is a [B5O12] unit with two BO3 triangles and three BO4 tetrahedra. 1 was characterized by single-crystal X-ray diffraction, IR and UV–Vis spectroscopy, thermogravimetric analysis (TGA), powder X-ray diffraction (PXRD) respectively. Also, powder second harmonic generation (SHG) measurements indicate that 1 is phase matchable and displays a SHG response of about 3.5 times that of KDP (KH2PO4).
UR - http://www.scopus.com/inward/record.url?scp=85034074746&partnerID=8YFLogxK
U2 - 10.1016/j.inoche.2017.11.006
DO - 10.1016/j.inoche.2017.11.006
M3 - Article
AN - SCOPUS:85034074746
SN - 1387-7003
VL - 86
SP - 308
EP - 311
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
ER -