TY - JOUR
T1 - Synthesis of two new cage molecules containing trinitromethyl group
AU - Sun, Cheng Hui
AU - Zhao, Xin Qi
AU - Li, Yu Chuan
AU - Pang, Si Ping
PY - 2010/5
Y1 - 2010/5
N2 - Two new cage compounds, 4-trinitroethyl-10-nitro-2,6,8,12-tetraacetylhexaazaisowurtzitane (3) and 4-trinitroethyl-2,6,8,10,12-pentanitrohexaazaisowurtzitane (4), containing trinitromethyl group were synthesized by a novel method, and their structures were confirmed by IR, 1H NMR, MS and single crystal X-ray. DSC result shows that compound 4 has surprising thermal stability and could be a potential energetic compound.
AB - Two new cage compounds, 4-trinitroethyl-10-nitro-2,6,8,12-tetraacetylhexaazaisowurtzitane (3) and 4-trinitroethyl-2,6,8,10,12-pentanitrohexaazaisowurtzitane (4), containing trinitromethyl group were synthesized by a novel method, and their structures were confirmed by IR, 1H NMR, MS and single crystal X-ray. DSC result shows that compound 4 has surprising thermal stability and could be a potential energetic compound.
KW - Cage compound
KW - Synthesis
KW - Trinitromethyl group
KW - X-ray crystal structure
UR - http://www.scopus.com/inward/record.url?scp=77949915819&partnerID=8YFLogxK
U2 - 10.1016/j.cclet.2009.12.001
DO - 10.1016/j.cclet.2009.12.001
M3 - Article
AN - SCOPUS:77949915819
SN - 1001-8417
VL - 21
SP - 572
EP - 575
JO - Chinese Chemical Letters
JF - Chinese Chemical Letters
IS - 5
ER -