Synthesis of two heterobimetallic complexes (dppe)PdMS4 (M = W, Mo), and X-ray structure of the tungsten complex

Biao Wu; Wenjian Zhang; Xiaoying Huang; Xintao Wu; Shuyan Yu

doi:10.1016/S0277-5387(96)00340-3

Synthesis of two heterobimetallic complexes (dppe)PdMS₄ (M = W, Mo), and X-ray structure of the tungsten complex

Biao Wu^*, Wenjian Zhang, Xiaoying Huang, Xintao Wu, Shuyan Yu

^*此作品的通讯作者

CAS - Fujian Institute of Research on the Structure of Matter

科研成果: 期刊稿件 › 文章 › 同行评审

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The heterobimetallic complexes (dppe)PdMS₄ [dppe = (CH₂PPh₂)₂. M = W. Mo] have been synthesized by the reaction of (dppe)PdCl₂ and (NH₄)₂MS₄ in CH₂Cl₂-CH₃CN solvent, and characterized by elemental analysis, UV-vis and IR spectroscopies. The structure of (dppe)PdWS₄ has been determined by single-crystal X-ray analysis. The Pd - W distance is 2.89 Å, the average distance of the W - S bridge is 2.23 Å. and that of terminal W - S is 2.14 Å.

源语言	英语
页（从-至）	801-804
页数	4
期刊	Polyhedron
卷	16
期	5
DOI	https://doi.org/10.1016/S0277-5387(96)00340-3
出版状态	已出版 - 4 12月 1996
已对外发布	是

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@article{e7aa4f2055934208ab8216b1859a8b4f,

title = "Synthesis of two heterobimetallic complexes (dppe)PdMS4 (M = W, Mo), and X-ray structure of the tungsten complex",

abstract = "The heterobimetallic complexes (dppe)PdMS4 [dppe = (CH2PPh2)2. M = W. Mo] have been synthesized by the reaction of (dppe)PdCl2 and (NH4)2MS4 in CH2Cl2-CH3CN solvent, and characterized by elemental analysis, UV-vis and IR spectroscopies. The structure of (dppe)PdWS4 has been determined by single-crystal X-ray analysis. The Pd - W distance is 2.89 {\AA}, the average distance of the W - S bridge is 2.23 {\AA}. and that of terminal W - S is 2.14 {\AA}.",

keywords = "Heterobimetallic, Palladium, Structure, Synthesis, Tetrathiometallate",

author = "Biao Wu and Wenjian Zhang and Xiaoying Huang and Xintao Wu and Shuyan Yu",

year = "1996",

month = dec,

day = "4",

doi = "10.1016/S0277-5387(96)00340-3",

language = "English",

volume = "16",

pages = "801--804",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

number = "5",

}

TY - JOUR

T1 - Synthesis of two heterobimetallic complexes (dppe)PdMS4 (M = W, Mo), and X-ray structure of the tungsten complex

AU - Wu, Biao

AU - Zhang, Wenjian

AU - Huang, Xiaoying

AU - Wu, Xintao

AU - Yu, Shuyan

PY - 1996/12/4

Y1 - 1996/12/4

N2 - The heterobimetallic complexes (dppe)PdMS4 [dppe = (CH2PPh2)2. M = W. Mo] have been synthesized by the reaction of (dppe)PdCl2 and (NH4)2MS4 in CH2Cl2-CH3CN solvent, and characterized by elemental analysis, UV-vis and IR spectroscopies. The structure of (dppe)PdWS4 has been determined by single-crystal X-ray analysis. The Pd - W distance is 2.89 Å, the average distance of the W - S bridge is 2.23 Å. and that of terminal W - S is 2.14 Å.

AB - The heterobimetallic complexes (dppe)PdMS4 [dppe = (CH2PPh2)2. M = W. Mo] have been synthesized by the reaction of (dppe)PdCl2 and (NH4)2MS4 in CH2Cl2-CH3CN solvent, and characterized by elemental analysis, UV-vis and IR spectroscopies. The structure of (dppe)PdWS4 has been determined by single-crystal X-ray analysis. The Pd - W distance is 2.89 Å, the average distance of the W - S bridge is 2.23 Å. and that of terminal W - S is 2.14 Å.

KW - Heterobimetallic

KW - Palladium

KW - Structure

KW - Synthesis

KW - Tetrathiometallate

UR - http://www.scopus.com/inward/record.url?scp=0000269365&partnerID=8YFLogxK

U2 - 10.1016/S0277-5387(96)00340-3

DO - 10.1016/S0277-5387(96)00340-3

M3 - Article

AN - SCOPUS:0000269365

SN - 0277-5387

VL - 16

SP - 801

EP - 804

JO - Polyhedron

JF - Polyhedron

IS - 5

ER -

Synthesis of two heterobimetallic complexes (dppe)PdMS4 (M = W, Mo), and X-ray structure of the tungsten complex

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Synthesis of two heterobimetallic complexes (dppe)PdMS₄ (M = W, Mo), and X-ray structure of the tungsten complex