Synthesis of tetraazacalix[2]arene[2]-triazines: Tuning the cavity by the substituents on the bridging nitrogen atoms

Qi Qiang Wang; De Xian Wang; Hong Wei Ma; Mei Xiang Wang

doi:10.1021/ol062441e

Synthesis of tetraazacalix[2]arene[2]-triazines: Tuning the cavity by the substituents on the bridging nitrogen atoms

Qi Qiang Wang, De Xian Wang, Hong Wei Ma, Mei Xiang Wang^*

^*此作品的通讯作者

CAS - Institute of Chemistry

科研成果: 期刊稿件 › 文章 › 同行评审

55 引用（Scopus）

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(Chemical Equation Presented) A number of tetraazacalix[2]arene[2]triazines bearing different substituents on the bridging nitrogen atoms were synthesized efficiently using a fragment coupling strategy. The N-arylation of the parent azacalix[2]arene[2]triazine afforded tetra(arylaza)calix[2]arene[2]triazine in 91% yield. The introduction of different substituents on the bridging positions led to the regulation of the cavity of the resulting macrocyclic molecules.

源语言	英语
页（从-至）	5967-5970
页数	4
期刊	Organic Letters
卷	8
期	26
DOI	https://doi.org/10.1021/ol062441e
出版状态	已出版 - 21 12月 2006
已对外发布	是

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abstract = "(Chemical Equation Presented) A number of tetraazacalix[2]arene[2]triazines bearing different substituents on the bridging nitrogen atoms were synthesized efficiently using a fragment coupling strategy. The N-arylation of the parent azacalix[2]arene[2]triazine afforded tetra(arylaza)calix[2]arene[2]triazine in 91% yield. The introduction of different substituents on the bridging positions led to the regulation of the cavity of the resulting macrocyclic molecules.",

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AU - Wang, Qi Qiang

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AU - Ma, Hong Wei

AU - Wang, Mei Xiang

PY - 2006/12/21

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N2 - (Chemical Equation Presented) A number of tetraazacalix[2]arene[2]triazines bearing different substituents on the bridging nitrogen atoms were synthesized efficiently using a fragment coupling strategy. The N-arylation of the parent azacalix[2]arene[2]triazine afforded tetra(arylaza)calix[2]arene[2]triazine in 91% yield. The introduction of different substituents on the bridging positions led to the regulation of the cavity of the resulting macrocyclic molecules.

AB - (Chemical Equation Presented) A number of tetraazacalix[2]arene[2]triazines bearing different substituents on the bridging nitrogen atoms were synthesized efficiently using a fragment coupling strategy. The N-arylation of the parent azacalix[2]arene[2]triazine afforded tetra(arylaza)calix[2]arene[2]triazine in 91% yield. The introduction of different substituents on the bridging positions led to the regulation of the cavity of the resulting macrocyclic molecules.

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Synthesis of tetraazacalix[2]arene[2]-triazines: Tuning the cavity by the substituents on the bridging nitrogen atoms

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