Synthesis of ethylene-propylene copolymer and their structures

Yan Liu Dang, Yun Zhao*, Chao Xiang Wang, Qing Ze Jiao, Han Sheng Li, Qin Wu

*此作品的通讯作者

科研成果: 书/报告/会议事项章节会议稿件同行评审

摘要

This work reports copolymerization of ethylene-propylene (EP) using a novel phenoxy–ester ligated titanium catalyst. Copolymerization reactions were conducted in toluene at 70 °C with varied E/P flow ratios. Fourier transform infrared spectroscopy, X-ray diffractometer, nuclear magnetic resonance spectroscopy and differential scanning calorimetry analysis were performed to characterize the structures, compositions and glass transition temperatures of the copolymers. The results show that ethylene-propylene copolymers are random polymers and the link ratios of ethylene to propylene are between 0.89 and 1.26. The glass transition temperature of ethylene-propylene copolymer is -43.3 °C.

源语言英语
主期刊名Proceedings of 2014 International Conference on Material Science and Engineering
编辑Ping Chen
出版商Trans Tech Publications Ltd.
149-154
页数6
ISBN(电子版)9783038352600
DOI
出版状态已出版 - 2014
活动2014 International Conference on Material Science and Engineering, ICMSE2014 - Xi'an, 中国
期限: 8 8月 20149 8月 2014

出版系列

姓名Advanced Materials Research
1035
ISSN(印刷版)1022-6680
ISSN(电子版)1662-8985

会议

会议2014 International Conference on Material Science and Engineering, ICMSE2014
国家/地区中国
Xi'an
时期8/08/149/08/14

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