Synthesis of Cyanamides from Cyanogen Bromide under Mild Conditions through N-Cyanation of Allylic Tertiary Amines

Honggang Liang, Lingxiang Bao, Yao Du, Yiying Zhang, Siping Pang, Chenghui Sun*

*此作品的通讯作者

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3 引用 (Scopus)

摘要

Cyanamides were selectively formed through a one-step nucleophilic substitution reaction of allylic tertiary amines with cyanogen bromide. Because of the mild reaction conditions and good yields of the reaction, as well as the commercial availability of the starting materials, this new method represents a valuable tool for the synthesis of cyan-amides through an N-deallylation reaction and an N-cyanation reaction in one pot.

源语言英语
页(从-至)2675-2679
页数5
期刊Synlett
28
19
DOI
出版状态已出版 - 1 12月 2017

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