摘要
An efficient approach to synthesize 5,5′-azoxybistetrazoles has been achieved via the treatment of tetrazolyl triazenes with fuming nitric acid and acetic anhydride in a two-step one-pot reaction. Herein, 5,5′-azoxybistetrazole is proposed to be formed via a nitroso triazene intermediate generated from tetrazolyl triazene by nitration and de-oxygen rearrangement. All compounds were fully characterized using IR, 1H and 13C NMR spectroscopy, and HRMS. In the case of 2,2′-dimethyl-5,5′-azoxybistetrazole (2a), single crystal X-ray structuring and 15N NMR spectroscopy were also performed. The calculations predict that 2f has a detonation velocity of 8066 m s-1 and a detonation pressure of 25.8 GPa.
源语言 | 英语 |
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页(从-至) | 11512-11516 |
页数 | 5 |
期刊 | New Journal of Chemistry |
卷 | 41 |
期 | 20 |
DOI | |
出版状态 | 已出版 - 2017 |