Synthesis of 5,5′-azoxybistetrazole via nitration and de-oxygen rearrangement of triazene

Qi Wang, Tian Lu, Chenbin Wang, Guijuan Fan, Hongquan Yin, Fu Xue Chen*

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

6 引用 (Scopus)

摘要

An efficient approach to synthesize 5,5′-azoxybistetrazoles has been achieved via the treatment of tetrazolyl triazenes with fuming nitric acid and acetic anhydride in a two-step one-pot reaction. Herein, 5,5′-azoxybistetrazole is proposed to be formed via a nitroso triazene intermediate generated from tetrazolyl triazene by nitration and de-oxygen rearrangement. All compounds were fully characterized using IR, 1H and 13C NMR spectroscopy, and HRMS. In the case of 2,2′-dimethyl-5,5′-azoxybistetrazole (2a), single crystal X-ray structuring and 15N NMR spectroscopy were also performed. The calculations predict that 2f has a detonation velocity of 8066 m s-1 and a detonation pressure of 25.8 GPa.

源语言英语
页(从-至)11512-11516
页数5
期刊New Journal of Chemistry
41
20
DOI
出版状态已出版 - 2017

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