TY - JOUR
T1 - Synthesis of 2-D graphite-like and 3-D diamond-like silver(I) polymers with 1,3-imidazolidine-2-thione
AU - Zhu, Qinlei
AU - Huang, Rudan
AU - Xu, Yanqing
AU - Zhang, Jing
AU - Liu, Xi
PY - 2009/8
Y1 - 2009/8
N2 - Two metal-organic coordination polymers, [Ag 2(imdt) 3(OAc) 2] n (1) (imdt = 1,3-imidazolidine-2-thione, OAc = CH 3COO -) and [Ag(imdt)Cl] n (2), were synthesized under similar conditions by using Et 3N (triethylamine) as buffering agent. X-ray diffraction shows that 1 crystallizes in the monoclinic system, C2/c space group, a = 13.822(5) Å, b = 9.082(3) Å, c = 16.965(6) Å, V = 2114.2(14) Å 3, Z=8, D c = 2.012g cm -3. Compound 2 crystallizes in the orthorhombic system, P2 12 12 1 space group, a = 7.993(6) Å, b = 7.993(6) Å, c = 10.548(7) Å, V = 673.9(7) Å 3, Z = 4, D c = 2.419 g cm -3. Both 1 and 2 exhibit different architectures due to their different anions. Compound 1 shows a 2-D graphite-like network structure and 2 shows a 3-D diamond-like network structure.
AB - Two metal-organic coordination polymers, [Ag 2(imdt) 3(OAc) 2] n (1) (imdt = 1,3-imidazolidine-2-thione, OAc = CH 3COO -) and [Ag(imdt)Cl] n (2), were synthesized under similar conditions by using Et 3N (triethylamine) as buffering agent. X-ray diffraction shows that 1 crystallizes in the monoclinic system, C2/c space group, a = 13.822(5) Å, b = 9.082(3) Å, c = 16.965(6) Å, V = 2114.2(14) Å 3, Z=8, D c = 2.012g cm -3. Compound 2 crystallizes in the orthorhombic system, P2 12 12 1 space group, a = 7.993(6) Å, b = 7.993(6) Å, c = 10.548(7) Å, V = 673.9(7) Å 3, Z = 4, D c = 2.419 g cm -3. Both 1 and 2 exhibit different architectures due to their different anions. Compound 1 shows a 2-D graphite-like network structure and 2 shows a 3-D diamond-like network structure.
KW - 1,3-Imidazolidine-2-thione
KW - Crystal structure
KW - Silver polymers
UR - http://www.scopus.com/inward/record.url?scp=69949096691&partnerID=8YFLogxK
U2 - 10.1080/00958970902874268
DO - 10.1080/00958970902874268
M3 - Article
AN - SCOPUS:69949096691
SN - 0095-8972
VL - 62
SP - 2656
EP - 2664
JO - Journal of Coordination Chemistry
JF - Journal of Coordination Chemistry
IS - 16
ER -