TY - JOUR
T1 - Synthesis, crystal structure and thermal stability of a novel 3D microporous coordination polymer
T2 - Na2[Co(1,4-napdc) 2(DMF)2]
AU - Wu, Rui Feng
AU - Zhang, Tong Lai
AU - Zhang, Jian Guo
AU - Qiao, Xiao Jing
AU - Yang, Li
AU - Guo, Jin Yu
PY - 2006/10
Y1 - 2006/10
N2 - A new 3D inorganic-organic hybrid framework microporous material Na 2Co(1,4-napdc)2(DMF)2(1,4-napdc = napthalene-1,4-dicarboxylate), which is constructed by coordination of cobalt ion and sodium ions with napthalene-1,4-dicarboxylate and DMF, is synthesized under solvothermal conditions. Two bidentate-bridging and two chelate-bridged carboxylate link a cobalt (II) and two sodiums (I) to the dimer structure. The square grids constructed with the caged-laddered-shaped secondary building units (SBUs) built by Co-O-Na-O and Co-O-C-O bond and 1,4-napdc links stack over each other to generate infinite 3D networks, which have a microporous channel (11.05 × 11.05 Å2) along the crystallographic c-axis. The thermal stability of the compound was investigated by differential scanning calorimetric and thermogravimetric analysis. The complexes could be anticipated as potential heat-resistant energetic material.
AB - A new 3D inorganic-organic hybrid framework microporous material Na 2Co(1,4-napdc)2(DMF)2(1,4-napdc = napthalene-1,4-dicarboxylate), which is constructed by coordination of cobalt ion and sodium ions with napthalene-1,4-dicarboxylate and DMF, is synthesized under solvothermal conditions. Two bidentate-bridging and two chelate-bridged carboxylate link a cobalt (II) and two sodiums (I) to the dimer structure. The square grids constructed with the caged-laddered-shaped secondary building units (SBUs) built by Co-O-Na-O and Co-O-C-O bond and 1,4-napdc links stack over each other to generate infinite 3D networks, which have a microporous channel (11.05 × 11.05 Å2) along the crystallographic c-axis. The thermal stability of the compound was investigated by differential scanning calorimetric and thermogravimetric analysis. The complexes could be anticipated as potential heat-resistant energetic material.
UR - http://www.scopus.com/inward/record.url?scp=33749000350&partnerID=8YFLogxK
U2 - 10.1007/s11243-006-0076-3
DO - 10.1007/s11243-006-0076-3
M3 - Article
AN - SCOPUS:33749000350
SN - 0340-4285
VL - 31
SP - 874
EP - 878
JO - Transition Metal Chemistry
JF - Transition Metal Chemistry
IS - 7
ER -