Synthesis, crystal structure and sensitivity of [Mn (IMI) 6](CIO4)2

Yan Ren; Ying Jun Yan; Li Yang; Tong Lai Zhang; Jian Guo Zhang; Kai Bei Yu

Synthesis, crystal structure and sensitivity of [Mn (IMI) ₆](CIO₄)₂

Yan Ren^*, Ying Jun Yan, Li Yang, Tong Lai Zhang, Jian Guo Zhang, Kai Bei Yu

^*此作品的通讯作者

机电学院

科研成果: 期刊稿件 › 文章 › 同行评审

2 引用（Scopus）

摘要

An energetic compound [Mn (IMI )₆] (ClO₄ ) ₂ (IMI: imidazolium) was synthesized by reaction of imidazolium with Mn(ClO₄ )₂ in aqueous solution. Single crystal of [Mn (IMI )₆] (ClO₄ )₂ was obtained. The compound was characterized by elemental analysis, TG-DTG and single crystal X-ray diffraction analysis. The results show that the crystal belongs to a monoclinic system with P2(l)/n space group and cell parameters of a = 11.721(2)nm, 6=7. 2191(13)nm, c=16. 402(3)nm, β=90. 064(3)°,V=1387. 9(4)nm³; A = I. 585g/cm³; Z = 2; F(000)= 678, μ = 0. 160 mm, R₁ = 0. 0367, ωK₂ = 0. 1372. The title compound [Mn(IMI) ₆](C104)2 formed by [Mn(IMI)₆]²⁺ and (ClO4) belongs to an ionic compound. The central Mn(II) ion is six-coordinated with six imidazole molecules. At a heating rate of 10K/min, the thermal decomposition process of the title compound consists of one endothermic peak and one exothermic peak with 9. 9% residues. The mechanic sensitivity test results show that this compound is an insensitive energetic compound.

源语言	英语
页（从-至）	15-19
页数	5
期刊	Huozhayao Xuebao/Chinese Journal of Explosives and Propellants
卷	32
期	6
出版状态	已出版 - 2009

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@article{cbe736305a95467baff912c7db530c08,

title = "Synthesis, crystal structure and sensitivity of [Mn (IMI) 6](CIO4)2",

abstract = "An energetic compound [Mn (IMI )6] (ClO4 ) 2 (IMI: imidazolium) was synthesized by reaction of imidazolium with Mn(ClO4 )2 in aqueous solution. Single crystal of [Mn (IMI )6] (ClO4 )2 was obtained. The compound was characterized by elemental analysis, TG-DTG and single crystal X-ray diffraction analysis. The results show that the crystal belongs to a monoclinic system with P2(l)/n space group and cell parameters of a = 11.721(2)nm, 6=7. 2191(13)nm, c=16. 402(3)nm, β=90. 064(3)°,V=1387. 9(4)nm3; A = I. 585g/cm3; Z = 2; F(000)= 678, μ = 0. 160 mm, R1 = 0. 0367, ωK2 = 0. 1372. The title compound [Mn(IMI) 6](C104)2 formed by [Mn(IMI)6]2+ and (ClO4) belongs to an ionic compound. The central Mn(II) ion is six-coordinated with six imidazole molecules. At a heating rate of 10K/min, the thermal decomposition process of the title compound consists of one endothermic peak and one exothermic peak with 9. 9% residues. The mechanic sensitivity test results show that this compound is an insensitive energetic compound.",

keywords = "Crystal structure, Imidazolium, Manganese perchlorate, Physical chemistry, Thermal analysis",

author = "Yan Ren and Yan, {Ying Jun} and Li Yang and Zhang, {Tong Lai} and Zhang, {Jian Guo} and Yu, {Kai Bei}",

year = "2009",

language = "English",

volume = "32",

pages = "15--19",

journal = "Huozhayao Xuebao/Chinese Journal of Explosives and Propellants",

issn = "1007-7812",

publisher = "China Ordnance Industry Corporation",

number = "6",

}

TY - JOUR

T1 - Synthesis, crystal structure and sensitivity of [Mn (IMI) 6](CIO4)2

AU - Ren, Yan

AU - Yan, Ying Jun

AU - Yang, Li

AU - Zhang, Tong Lai

AU - Zhang, Jian Guo

AU - Yu, Kai Bei

PY - 2009

Y1 - 2009

N2 - An energetic compound [Mn (IMI )6] (ClO4 ) 2 (IMI: imidazolium) was synthesized by reaction of imidazolium with Mn(ClO4 )2 in aqueous solution. Single crystal of [Mn (IMI )6] (ClO4 )2 was obtained. The compound was characterized by elemental analysis, TG-DTG and single crystal X-ray diffraction analysis. The results show that the crystal belongs to a monoclinic system with P2(l)/n space group and cell parameters of a = 11.721(2)nm, 6=7. 2191(13)nm, c=16. 402(3)nm, β=90. 064(3)°,V=1387. 9(4)nm3; A = I. 585g/cm3; Z = 2; F(000)= 678, μ = 0. 160 mm, R1 = 0. 0367, ωK2 = 0. 1372. The title compound [Mn(IMI) 6](C104)2 formed by [Mn(IMI)6]2+ and (ClO4) belongs to an ionic compound. The central Mn(II) ion is six-coordinated with six imidazole molecules. At a heating rate of 10K/min, the thermal decomposition process of the title compound consists of one endothermic peak and one exothermic peak with 9. 9% residues. The mechanic sensitivity test results show that this compound is an insensitive energetic compound.

AB - An energetic compound [Mn (IMI )6] (ClO4 ) 2 (IMI: imidazolium) was synthesized by reaction of imidazolium with Mn(ClO4 )2 in aqueous solution. Single crystal of [Mn (IMI )6] (ClO4 )2 was obtained. The compound was characterized by elemental analysis, TG-DTG and single crystal X-ray diffraction analysis. The results show that the crystal belongs to a monoclinic system with P2(l)/n space group and cell parameters of a = 11.721(2)nm, 6=7. 2191(13)nm, c=16. 402(3)nm, β=90. 064(3)°,V=1387. 9(4)nm3; A = I. 585g/cm3; Z = 2; F(000)= 678, μ = 0. 160 mm, R1 = 0. 0367, ωK2 = 0. 1372. The title compound [Mn(IMI) 6](C104)2 formed by [Mn(IMI)6]2+ and (ClO4) belongs to an ionic compound. The central Mn(II) ion is six-coordinated with six imidazole molecules. At a heating rate of 10K/min, the thermal decomposition process of the title compound consists of one endothermic peak and one exothermic peak with 9. 9% residues. The mechanic sensitivity test results show that this compound is an insensitive energetic compound.

KW - Crystal structure

KW - Imidazolium

KW - Manganese perchlorate

KW - Physical chemistry

KW - Thermal analysis

UR - http://www.scopus.com/inward/record.url?scp=77950245971&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:77950245971

SN - 1007-7812

VL - 32

SP - 15

EP - 19

JO - Huozhayao Xuebao/Chinese Journal of Explosives and Propellants

JF - Huozhayao Xuebao/Chinese Journal of Explosives and Propellants

IS - 6

ER -

Synthesis, crystal structure and sensitivity of [Mn (IMI) 6](CIO4)2

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Synthesis, crystal structure and sensitivity of [Mn (IMI) ₆](CIO₄)₂