TY - JOUR
T1 - Synthesis, crystal structure and antibacterial activity of the complex di-μ2-hydroxyl-diacetic-di-μ3-oxo-octa-n-butyltetratin with 2D Layered
AU - Wang, Yan Hua
AU - Ye, Zhang Ji
AU - Jin, Xiao Hong
AU - Yao, Jing Hua
AU - Chen, Nai Hong
AU - Zhu, Dong Sheng
PY - 2008/1
Y1 - 2008/1
N2 - The complex 1, [systematic name 1,2,3,4-di-μ2-hydroxyl-1,4- diacetic-1,1,2,2,3,3,4,4-octa-n,-butyl-di-yu,3-oxo-tetratin(IV)], [Sn 4(C6H5)8(OH)2O2(CH 3COO)2], was synthesized and characterized by elemental analysis, 1H NMR, FTIR spectroscopy and X-ray diffraction single crystal struscture analysis. The symmetric dimer with a hydroxy bridged ladder consists of a central Sn2O2 ring with two additional adjacent Sn2(OH)O four-membered rings. The Sn, O and OH atoms are approximately coplanar; the Sn atoms exhibit a distorted trigonal-bipyramidal coordination configuration. The 2D layer is exhibited with chanels formed by the hydrogen-bonded (C-H⋯0). The antibacterial activity was preliminarily studied.
AB - The complex 1, [systematic name 1,2,3,4-di-μ2-hydroxyl-1,4- diacetic-1,1,2,2,3,3,4,4-octa-n,-butyl-di-yu,3-oxo-tetratin(IV)], [Sn 4(C6H5)8(OH)2O2(CH 3COO)2], was synthesized and characterized by elemental analysis, 1H NMR, FTIR spectroscopy and X-ray diffraction single crystal struscture analysis. The symmetric dimer with a hydroxy bridged ladder consists of a central Sn2O2 ring with two additional adjacent Sn2(OH)O four-membered rings. The Sn, O and OH atoms are approximately coplanar; the Sn atoms exhibit a distorted trigonal-bipyramidal coordination configuration. The 2D layer is exhibited with chanels formed by the hydrogen-bonded (C-H⋯0). The antibacterial activity was preliminarily studied.
KW - Antibacterial activity
KW - Crystal structure
KW - Di-μ-hydroxyl-diacetic-di-μ- oxo-octa-n-butyltetratin
KW - Organotin(IV)
UR - http://www.scopus.com/inward/record.url?scp=38949094330&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:38949094330
SN - 1001-4861
VL - 24
SP - 145
EP - 148
JO - Chinese Journal of Inorganic Chemistry
JF - Chinese Journal of Inorganic Chemistry
IS - 1
ER -