TY - JOUR
T1 - Synthesis, characterization, and thermal analysis of two energetic Ionic Salts based on 3,4-Diamino-1,2,4-triazole (DATr)
AU - Wu, Jin Ting
AU - Zhang, Jian Guo
AU - Yin, Xin
AU - Sun, Mou
AU - Zhang, Tong Lai
PY - 2013/10
Y1 - 2013/10
N2 - Two energetic ionic salts DATr·NTO (2) and DATr·TNR (3) of 3,4-diamino-1,2,4-triazole (DATr) (1) were synthesized by reaction of 3,4-diamino-1,2,4-triazole with either 3-nitro-1,2,4-triazole-5-one (NTO) or 2,4,6-trinitro-resorcinol (TNR) in aqueous solution. Their structures were characterized by FT IR spectroscopy (FT-IR) and Xray single-crystal diffraction analysis. Their molecular structure and crystal structure were determined. They belong to the monoclinic crys- tal system, space group P21/c. The crystal density is 1.693 g·cm-3 and 1.738 g·cm-3, respectively. The thermal decomposition characteristics of the title compounds were investigated using differential scanning calorimetry (DSC) and thermogravimetry/differential thermogravimetry (TG/DTG) technologies. Furthermore, the sensitivity properties were determined by standard methods.
AB - Two energetic ionic salts DATr·NTO (2) and DATr·TNR (3) of 3,4-diamino-1,2,4-triazole (DATr) (1) were synthesized by reaction of 3,4-diamino-1,2,4-triazole with either 3-nitro-1,2,4-triazole-5-one (NTO) or 2,4,6-trinitro-resorcinol (TNR) in aqueous solution. Their structures were characterized by FT IR spectroscopy (FT-IR) and Xray single-crystal diffraction analysis. Their molecular structure and crystal structure were determined. They belong to the monoclinic crys- tal system, space group P21/c. The crystal density is 1.693 g·cm-3 and 1.738 g·cm-3, respectively. The thermal decomposition characteristics of the title compounds were investigated using differential scanning calorimetry (DSC) and thermogravimetry/differential thermogravimetry (TG/DTG) technologies. Furthermore, the sensitivity properties were determined by standard methods.
KW - 3-4-Diamino-1-2-4-triazole-3-Nitro-1-2-4-triazole-5-one-2-4-6-Trinitro- resorcinol-Crystal structure-Thermal analysis-Energetic compounds-Sensitivity test
UR - http://www.scopus.com/inward/record.url?scp=84898773172&partnerID=8YFLogxK
U2 - 10.1002/zaac.201300247
DO - 10.1002/zaac.201300247
M3 - Article
AN - SCOPUS:84898773172
SN - 0044-2313
VL - 639
SP - 2354
EP - 2358
JO - Zeitschrift fur Anorganische und Allgemeine Chemie
JF - Zeitschrift fur Anorganische und Allgemeine Chemie
IS - 12-13
ER -