TY - JOUR
T1 - Synthesis, characterization, and magnetic properties of a coordination polymer of nickel
T2 - Poly[μ4-dicyanamide-(2,9-dimethyl-1,10- phenanthroline-κ2N,N')nickel(II)]
AU - Liu, Tian Fu
AU - Bao, Zhongming
AU - Li, Ling Ling
PY - 2011/3/20
Y1 - 2011/3/20
N2 - A new coordination polymer of Ni2+, N(CN)2 - (dicyanamide, herein denoted dca) and 2,9-dimethyl-1,10- phenanthroline (dmphen), has been synthesized, structurally and magnetically characterized. {[Ni2(dmphen)2[μ-dca]4} n (1), which crystallizes in the monoclinic space group P2 1/n, has a 2-D network that consists of double-bridged [Ni 2(dca)2(dmphen)2]2+ dimers connected via single-bridging dca ligands and exhibits a typical (6, 3) topological network. Each NiN6 octahedron comprises a bidentate dmphen and four μ1,5-bridging dca anions. Magnetic susceptibility measurements indicate antiferromagnetic interactions between Ni(II) ions via the dca bridge.
AB - A new coordination polymer of Ni2+, N(CN)2 - (dicyanamide, herein denoted dca) and 2,9-dimethyl-1,10- phenanthroline (dmphen), has been synthesized, structurally and magnetically characterized. {[Ni2(dmphen)2[μ-dca]4} n (1), which crystallizes in the monoclinic space group P2 1/n, has a 2-D network that consists of double-bridged [Ni 2(dca)2(dmphen)2]2+ dimers connected via single-bridging dca ligands and exhibits a typical (6, 3) topological network. Each NiN6 octahedron comprises a bidentate dmphen and four μ1,5-bridging dca anions. Magnetic susceptibility measurements indicate antiferromagnetic interactions between Ni(II) ions via the dca bridge.
KW - 2,9-Dimethyl-1,10-phenanthroline
KW - Dicyanamide
KW - Magnetic property
KW - Nickel(II) compound
KW - X-ray structure
UR - http://www.scopus.com/inward/record.url?scp=79952599569&partnerID=8YFLogxK
U2 - 10.1080/00958972.2011.560938
DO - 10.1080/00958972.2011.560938
M3 - Article
AN - SCOPUS:79952599569
SN - 0095-8972
VL - 64
SP - 1063
EP - 1068
JO - Journal of Coordination Chemistry
JF - Journal of Coordination Chemistry
IS - 6
ER -