TY - JOUR
T1 - Synthesis, Characterization, and Energetic Properties of N-Rich Salts of the 4,5-Dicyano-2H-1,2,3-triazole Anion
AU - Zhang, Yinghao
AU - Du, Zhiming
AU - Han, Zhiyue
AU - Zhao, Zhihua
AU - Yao, Qian
N1 - Publisher Copyright:
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
PY - 2015/12/1
Y1 - 2015/12/1
N2 - The synthesis and characterization of the 4,5-dicyano-2H-1,2,3-triazole anion in its 5-aminotetrazole, 1,5-diaminotetrazole, and 1,5-diamino-4-methyl-tetrazole salts are reported. All compounds were characterized by IR, 1H NMR, and 13C NMR spectroscopy, as well as elemental analyses. Their thermal decompositions were investigated by TG-DSC. The densities, combustion heats, and sensitivity properties were tested. Additionally, enthalpies of formation, detonation pressures, detonation velocities, and heats of detonation were calculated. The compounds have potential application in the energetic materials field.
AB - The synthesis and characterization of the 4,5-dicyano-2H-1,2,3-triazole anion in its 5-aminotetrazole, 1,5-diaminotetrazole, and 1,5-diamino-4-methyl-tetrazole salts are reported. All compounds were characterized by IR, 1H NMR, and 13C NMR spectroscopy, as well as elemental analyses. Their thermal decompositions were investigated by TG-DSC. The densities, combustion heats, and sensitivity properties were tested. Additionally, enthalpies of formation, detonation pressures, detonation velocities, and heats of detonation were calculated. The compounds have potential application in the energetic materials field.
KW - 4,5-Dicyano-1,2,3-triazole
KW - Characterization
KW - Energetic properties
KW - N-Rich salts
KW - Synthesis
UR - http://www.scopus.com/inward/record.url?scp=84956999235&partnerID=8YFLogxK
U2 - 10.1002/prep.201500112
DO - 10.1002/prep.201500112
M3 - Article
AN - SCOPUS:84956999235
SN - 0721-3115
VL - 40
SP - 960
EP - 964
JO - Propellants, Explosives, Pyrotechnics
JF - Propellants, Explosives, Pyrotechnics
IS - 6
ER -