TY - JOUR
T1 - Synthesis and X-ray structure of dichlorobis(8-(diphenylphosphinyl)quinoline)nickel(II)
AU - Li, Zilong
AU - Sun, Wen Hua
AU - Wang, Leyong
AU - Wu, Biao
AU - He, Cheng
AU - Yan, Chunhua
PY - 2002
Y1 - 2002
N2 - Dichlorobis(8-(diphenylphosphinyl)quinoline)nickel(II) was formed in the reaction of 8-(diphenylphosphino)quinoline with nickel chloride in air. The title complex crystallized in P1 with the following cell dimensions: a = 8.5685(3) Å, b = 10.7736(2) Å, c = 13.4391(5) Å, and α = 110.447(2)°, β = 94.577(2)°; γ = 111.138(2)°, giving a volume of 1053.75(6) Å3. The trans-dichlorobis(8-(diphenylphosphinyl)quinoline) nickel(II) adapts a central symmetric distorted octahedron. The structure is compared to other nickel(II) cation complexes, and possible reasons for the bonding states are discussed.
AB - Dichlorobis(8-(diphenylphosphinyl)quinoline)nickel(II) was formed in the reaction of 8-(diphenylphosphino)quinoline with nickel chloride in air. The title complex crystallized in P1 with the following cell dimensions: a = 8.5685(3) Å, b = 10.7736(2) Å, c = 13.4391(5) Å, and α = 110.447(2)°, β = 94.577(2)°; γ = 111.138(2)°, giving a volume of 1053.75(6) Å3. The trans-dichlorobis(8-(diphenylphosphinyl)quinoline) nickel(II) adapts a central symmetric distorted octahedron. The structure is compared to other nickel(II) cation complexes, and possible reasons for the bonding states are discussed.
KW - 8-(Diphenylphosphino)quinoline
KW - Nickel chloride
KW - X-ray single crystal structure
UR - http://www.scopus.com/inward/record.url?scp=0036269736&partnerID=8YFLogxK
U2 - 10.1023/A:1015673100877
DO - 10.1023/A:1015673100877
M3 - Article
AN - SCOPUS:0036269736
SN - 1074-1542
VL - 32
SP - 107
EP - 111
JO - Journal of Chemical Crystallography
JF - Journal of Chemical Crystallography
IS - 5-6
ER -