Synthesis and crystal structure of the cryptate complex [Gd(L)(DMF)] · KSCN · CH3CN · 3H2O (L is a deprotonated phenol-based N8O3 cryptand)

Shu Yan Yu, Quan Ming Wang, Biao Wu, Xin Tao Wu*, Huai Ming Hu, Liu Fang Wang, An Xin Wu

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

16 引用 (Scopus)

摘要

The cryptate complex [Gd(L)(DMF)] · KSCN · CH3CN · 3H2O has been synthesized by the reaction of gadolinium isothiocyanate and potassium thiocyanate with cryptate [Na(H2L)], which was prepared by a (2 + 3) Schiff-base condensation of tris(2-aminoethyl)amine and 2,6-diformyl-4-methoxyphenol in the presence of NaOH. The Gd atom is encapsulated in the cryptand with an unsymmetric eight-coordinate environment.

源语言英语
页(从-至)321-325
页数5
期刊Polyhedron
16
2
DOI
出版状态已出版 - 1997
已对外发布

指纹

探究 'Synthesis and crystal structure of the cryptate complex [Gd(L)(DMF)] · KSCN · CH3CN · 3H2O (L is a deprotonated phenol-based N8O3 cryptand)' 的科研主题。它们共同构成独一无二的指纹。

引用此