Synthesis and crystal structure of complex [Ni(en)3] 4[HVIV12VV6O 42(PO4)]

Shou Tian Zheng, Qing Xin Zeng, Zhi En Lin, Guo Yu Yang*

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

1 引用 (Scopus)

摘要

A new complex [Ni(en)3]4[HVIV 12VV6O42(PO4)] has been hydrothermally synthesized and characterized by X-Ray diffraction, IR and Elemental analysis. Single crystal X-ray analysis indicates that this compoud crystallizes in cubic system, space group Im 3m with a = 17.4081(2) Å, V = 5275.38(10) Å3, R = 0.0420, wR = 0.1055, Z = 2, Dc = 1.663g · cm-3, μ = 2.297mm-1, F(000) = 2636. The crystal structure consists of [Ni(en)3]2+ cations and {HV18O42(PO4)}8- cluster anion which construct from 18 {VO5} square pyramids. The VO5 pyramids joined each other to form a {V18O42} cage hosting a tetrahedral {PO4}3- moiety with disordered oxygen atoms. CCDC: 185574.

源语言英语
页(从-至)1233-1236
页数4
期刊Chinese Journal of Inorganic Chemistry
18
12
出版状态已出版 - 2002
已对外发布

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