摘要
A new complex [Ni(en)3]4[HVIV 12VV6O42(PO4)] has been hydrothermally synthesized and characterized by X-Ray diffraction, IR and Elemental analysis. Single crystal X-ray analysis indicates that this compoud crystallizes in cubic system, space group Im 3m with a = 17.4081(2) Å, V = 5275.38(10) Å3, R = 0.0420, wR = 0.1055, Z = 2, Dc = 1.663g · cm-3, μ = 2.297mm-1, F(000) = 2636. The crystal structure consists of [Ni(en)3]2+ cations and {HV18O42(PO4)}8- cluster anion which construct from 18 {VO5} square pyramids. The VO5 pyramids joined each other to form a {V18O42} cage hosting a tetrahedral {PO4}3- moiety with disordered oxygen atoms. CCDC: 185574.
源语言 | 英语 |
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页(从-至) | 1233-1236 |
页数 | 4 |
期刊 | Chinese Journal of Inorganic Chemistry |
卷 | 18 |
期 | 12 |
出版状态 | 已出版 - 2002 |
已对外发布 | 是 |