Synthesis and crystal structure of a novel 2D Cadmium(II) complex constructed from N-(3-Carboxyphenyl)-4,4'-bipyridinium and Benzene-l,4- dicarboxylic acid

Wei Wu; Xu Hui Jin; Zhang Feng Ju; Jie Zhang

Synthesis and crystal structure of a novel 2D Cadmium(II) complex constructed from N-(3-Carboxyphenyl)-4,4'-bipyridinium and Benzene-l,4- dicarboxylic acid

Wei Wu, Xu Hui Jin, Zhang Feng Ju, Jie Zhang^*

^*此作品的通讯作者

CAS - Fujian Institute of Research on the Structure of Matter

科研成果: 期刊稿件 › 文章 › 同行评审

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摘要

A novel redox-active bipyridinium ligand N-(3-carboxyphenyl)-4,4'- bipyridinium chloride (HCPBPyCl) and its coordination polymer {[Cd ₂(CPBPy) ₂(BDC)(H ₂O) ₂Cl ₂]·6H ₂O} _n 1 (H ₂BDC = benzene-1,4-dicarboxylic acid) were synthesized and characterized. Crystallographic data for 1: C ₄₂H ₄₄Cd ₂Cl ₂N ₄O ₁₆, M _r = 1156.51, monoclinic, space group C2/c, a = 21.046(3), b = 11.0036(15), c = 20.012(3) Å, β = 98.694(8)°, Z = 4, V= 4581.1(11) Å ³, D _c = 1.677 g/cm ³, F(000) = 2280 and μ = 1.120 mm ^-1. Complex 1 possesses a thick and undulated two-dimensional layer with (6,3) topology, which interpenetrates with two others (above and below) to extend into a three-dimensional supramolecular framework.

源语言	英语
页（从-至）	949-954
页数	6
期刊	Jiegou Huaxue
卷	27
期	8
出版状态	已出版 - 2008
已对外发布	是

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@article{2a3c1567d49d4b3ea533fae09e85d651,

title = "Synthesis and crystal structure of a novel 2D Cadmium(II) complex constructed from N-(3-Carboxyphenyl)-4,4'-bipyridinium and Benzene-l,4- dicarboxylic acid",

abstract = "A novel redox-active bipyridinium ligand N-(3-carboxyphenyl)-4,4'- bipyridinium chloride (HCPBPyCl) and its coordination polymer {[Cd 2(CPBPy) 2(BDC)(H 2O) 2Cl 2]·6H 2O} n 1 (H 2BDC = benzene-1,4-dicarboxylic acid) were synthesized and characterized. Crystallographic data for 1: C 42H 44Cd 2Cl 2N 4O 16, M r = 1156.51, monoclinic, space group C2/c, a = 21.046(3), b = 11.0036(15), c = 20.012(3) {\AA}, β = 98.694(8)°, Z = 4, V= 4581.1(11) {\AA} 3, D c = 1.677 g/cm 3, F(000) = 2280 and μ = 1.120 mm -1. Complex 1 possesses a thick and undulated two-dimensional layer with (6,3) topology, which interpenetrates with two others (above and below) to extend into a three-dimensional supramolecular framework.",

keywords = "4-dicarboxulic acid, Benzene-1, Bipyridinium, Cadimium, Crystal structure",

author = "Wei Wu and Jin, {Xu Hui} and Ju, {Zhang Feng} and Jie Zhang",

year = "2008",

language = "English",

volume = "27",

pages = "949--954",

journal = "Jiegou Huaxue",

issn = "0254-5861",

publisher = "Fujian Institute of Research of the Structure of Matter",

number = "8",

}

TY - JOUR

T1 - Synthesis and crystal structure of a novel 2D Cadmium(II) complex constructed from N-(3-Carboxyphenyl)-4,4'-bipyridinium and Benzene-l,4- dicarboxylic acid

AU - Wu, Wei

AU - Jin, Xu Hui

AU - Ju, Zhang Feng

AU - Zhang, Jie

PY - 2008

Y1 - 2008

N2 - A novel redox-active bipyridinium ligand N-(3-carboxyphenyl)-4,4'- bipyridinium chloride (HCPBPyCl) and its coordination polymer {[Cd 2(CPBPy) 2(BDC)(H 2O) 2Cl 2]·6H 2O} n 1 (H 2BDC = benzene-1,4-dicarboxylic acid) were synthesized and characterized. Crystallographic data for 1: C 42H 44Cd 2Cl 2N 4O 16, M r = 1156.51, monoclinic, space group C2/c, a = 21.046(3), b = 11.0036(15), c = 20.012(3) Å, β = 98.694(8)°, Z = 4, V= 4581.1(11) Å 3, D c = 1.677 g/cm 3, F(000) = 2280 and μ = 1.120 mm -1. Complex 1 possesses a thick and undulated two-dimensional layer with (6,3) topology, which interpenetrates with two others (above and below) to extend into a three-dimensional supramolecular framework.

AB - A novel redox-active bipyridinium ligand N-(3-carboxyphenyl)-4,4'- bipyridinium chloride (HCPBPyCl) and its coordination polymer {[Cd 2(CPBPy) 2(BDC)(H 2O) 2Cl 2]·6H 2O} n 1 (H 2BDC = benzene-1,4-dicarboxylic acid) were synthesized and characterized. Crystallographic data for 1: C 42H 44Cd 2Cl 2N 4O 16, M r = 1156.51, monoclinic, space group C2/c, a = 21.046(3), b = 11.0036(15), c = 20.012(3) Å, β = 98.694(8)°, Z = 4, V= 4581.1(11) Å 3, D c = 1.677 g/cm 3, F(000) = 2280 and μ = 1.120 mm -1. Complex 1 possesses a thick and undulated two-dimensional layer with (6,3) topology, which interpenetrates with two others (above and below) to extend into a three-dimensional supramolecular framework.

KW - 4-dicarboxulic acid

KW - Benzene-1

KW - Bipyridinium

KW - Cadimium

KW - Crystal structure

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M3 - Article

AN - SCOPUS:76649136481

SN - 0254-5861

VL - 27

SP - 949

EP - 954

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 8

ER -

Synthesis and crystal structure of a novel 2D Cadmium(II) complex constructed from N-(3-Carboxyphenyl)-4,4'-bipyridinium and Benzene-l,4- dicarboxylic acid

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