Synthesis and characterization of uniformly dispersed Fe3O 4/Fe nanocomposite on porous carbon: Application for rechargeable Li-O2 batteries

Jun Lu; Yan Qin; Peng Du; Xiangyi Luo; Tianpin Wu; Yang Ren; Jianguo Wen; Dean J. Miller; Jeffrey T. Miller; Khalil Amine

doi:10.1039/c3ra40451j

Synthesis and characterization of uniformly dispersed Fe₃O ₄/Fe nanocomposite on porous carbon: Application for rechargeable Li-O₂ batteries

Jun Lu, Yan Qin, Peng Du, Xiangyi Luo, Tianpin Wu, Yang Ren, Jianguo Wen, Dean J. Miller, Jeffrey T. Miller, Khalil Amine^*

^*此作品的通讯作者

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53 引用（Scopus）

摘要

Uniformly dispersed core-shelled Fe/Fe₃O₄ nanocomposite on porous carbon was synthesized via a wet-chemistry approach, which was tested as a cathode material in rechargeable Li-O₂ battery, showing highly active catalytic effect towards the electrochemical reactions, of particular, oxygen reduction reaction. XPS data showed the oxygen reduction reaction took place on the surface of the catalyst during discharge of the cell. Both XRD and XPS data demonstrated that lithium peroxide partook in the reversible reactions in the Li-O₂ cell with a TEGDME-based electrolyte.

源语言	英语
页（从-至）	8276-8285
页数	10
期刊	RSC Advances
卷	3
期	22
DOI	https://doi.org/10.1039/c3ra40451j
出版状态	已出版 - 2013
已对外发布	是

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title = "Synthesis and characterization of uniformly dispersed Fe3O 4/Fe nanocomposite on porous carbon: Application for rechargeable Li-O2 batteries",

abstract = "Uniformly dispersed core-shelled Fe/Fe3O4 nanocomposite on porous carbon was synthesized via a wet-chemistry approach, which was tested as a cathode material in rechargeable Li-O2 battery, showing highly active catalytic effect towards the electrochemical reactions, of particular, oxygen reduction reaction. XPS data showed the oxygen reduction reaction took place on the surface of the catalyst during discharge of the cell. Both XRD and XPS data demonstrated that lithium peroxide partook in the reversible reactions in the Li-O2 cell with a TEGDME-based electrolyte.",

author = "Jun Lu and Yan Qin and Peng Du and Xiangyi Luo and Tianpin Wu and Yang Ren and Jianguo Wen and Miller, {Dean J.} and Miller, {Jeffrey T.} and Khalil Amine",

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T1 - Synthesis and characterization of uniformly dispersed Fe3O 4/Fe nanocomposite on porous carbon

T2 - Application for rechargeable Li-O2 batteries

AU - Lu, Jun

AU - Qin, Yan

AU - Du, Peng

AU - Luo, Xiangyi

AU - Wu, Tianpin

AU - Ren, Yang

AU - Wen, Jianguo

AU - Miller, Dean J.

AU - Miller, Jeffrey T.

AU - Amine, Khalil

PY - 2013

Y1 - 2013

N2 - Uniformly dispersed core-shelled Fe/Fe3O4 nanocomposite on porous carbon was synthesized via a wet-chemistry approach, which was tested as a cathode material in rechargeable Li-O2 battery, showing highly active catalytic effect towards the electrochemical reactions, of particular, oxygen reduction reaction. XPS data showed the oxygen reduction reaction took place on the surface of the catalyst during discharge of the cell. Both XRD and XPS data demonstrated that lithium peroxide partook in the reversible reactions in the Li-O2 cell with a TEGDME-based electrolyte.

AB - Uniformly dispersed core-shelled Fe/Fe3O4 nanocomposite on porous carbon was synthesized via a wet-chemistry approach, which was tested as a cathode material in rechargeable Li-O2 battery, showing highly active catalytic effect towards the electrochemical reactions, of particular, oxygen reduction reaction. XPS data showed the oxygen reduction reaction took place on the surface of the catalyst during discharge of the cell. Both XRD and XPS data demonstrated that lithium peroxide partook in the reversible reactions in the Li-O2 cell with a TEGDME-based electrolyte.

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JO - RSC Advances

JF - RSC Advances

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Synthesis and characterization of uniformly dispersed Fe3O 4/Fe nanocomposite on porous carbon: Application for rechargeable Li-O2 batteries

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Synthesis and characterization of uniformly dispersed Fe₃O ₄/Fe nanocomposite on porous carbon: Application for rechargeable Li-O₂ batteries