Synthesis and characterization of PBAMO/GAP tri-block copolymer

Yi Bo Zhao; Yun Jun Luo; Xiao Meng Li; Zhen Ge

Synthesis and characterization of PBAMO/GAP tri-block copolymer

Yi Bo Zhao, Yun Jun Luo^*, Xiao Meng Li, Zhen Ge

^*此作品的通讯作者

材料学院

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

6 引用（Scopus）

摘要

The tri-block copolymer of glycidyl azide polymer (GAP) and poly(bis(azidomethyl)oxetane (PBAMO) was synthesized by cationic ring opening polymerization with the borontrifluoridedimethyl ether complex as catalyst and the GAP as initiator. The structure and the thermal properties of the copolymer were characterized by IR, ¹HNMR, GPC, DSC and TG. The results show that the molecular weight of the copolymer is controlled, the functionality is agree with the calculation, and the tri-block copolymer exhibits the characteristics of an ETPE. The decomposition of the copolymer begins at 229°C, which means that the copolymer has good thermal stability.

源语言	英语
页（从-至）	58-61
页数	4
期刊	Huozhayao Xuebao/Chinese Journal of Explosives and Propellants
卷	35
期	2
出版状态	已出版 - 4月 2012

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title = "Synthesis and characterization of PBAMO/GAP tri-block copolymer",

abstract = "The tri-block copolymer of glycidyl azide polymer (GAP) and poly(bis(azidomethyl)oxetane (PBAMO) was synthesized by cationic ring opening polymerization with the borontrifluoridedimethyl ether complex as catalyst and the GAP as initiator. The structure and the thermal properties of the copolymer were characterized by IR, 1HNMR, GPC, DSC and TG. The results show that the molecular weight of the copolymer is controlled, the functionality is agree with the calculation, and the tri-block copolymer exhibits the characteristics of an ETPE. The decomposition of the copolymer begins at 229°C, which means that the copolymer has good thermal stability.",

keywords = "Energetic binders, Energetic thermalplastic elastomer, GAP, Material science, PBAMO, Solid propellant",

author = "Zhao, {Yi Bo} and Luo, {Yun Jun} and Li, {Xiao Meng} and Zhen Ge",

year = "2012",

month = apr,

language = "English",

volume = "35",

pages = "58--61",

journal = "Huozhayao Xuebao/Chinese Journal of Explosives and Propellants",

issn = "1007-7812",

publisher = "China Ordnance Industry Corporation",

number = "2",

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TY - JOUR

T1 - Synthesis and characterization of PBAMO/GAP tri-block copolymer

AU - Zhao, Yi Bo

AU - Luo, Yun Jun

AU - Li, Xiao Meng

AU - Ge, Zhen

PY - 2012/4

Y1 - 2012/4

N2 - The tri-block copolymer of glycidyl azide polymer (GAP) and poly(bis(azidomethyl)oxetane (PBAMO) was synthesized by cationic ring opening polymerization with the borontrifluoridedimethyl ether complex as catalyst and the GAP as initiator. The structure and the thermal properties of the copolymer were characterized by IR, 1HNMR, GPC, DSC and TG. The results show that the molecular weight of the copolymer is controlled, the functionality is agree with the calculation, and the tri-block copolymer exhibits the characteristics of an ETPE. The decomposition of the copolymer begins at 229°C, which means that the copolymer has good thermal stability.

AB - The tri-block copolymer of glycidyl azide polymer (GAP) and poly(bis(azidomethyl)oxetane (PBAMO) was synthesized by cationic ring opening polymerization with the borontrifluoridedimethyl ether complex as catalyst and the GAP as initiator. The structure and the thermal properties of the copolymer were characterized by IR, 1HNMR, GPC, DSC and TG. The results show that the molecular weight of the copolymer is controlled, the functionality is agree with the calculation, and the tri-block copolymer exhibits the characteristics of an ETPE. The decomposition of the copolymer begins at 229°C, which means that the copolymer has good thermal stability.

KW - Energetic binders

KW - Energetic thermalplastic elastomer

KW - GAP

KW - Material science

KW - PBAMO

KW - Solid propellant

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M3 - Article

AN - SCOPUS:84861777223

SN - 1007-7812

VL - 35

SP - 58

EP - 61

JO - Huozhayao Xuebao/Chinese Journal of Explosives and Propellants

JF - Huozhayao Xuebao/Chinese Journal of Explosives and Propellants

IS - 2

ER -

Synthesis and characterization of PBAMO/GAP tri-block copolymer

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