TY - JOUR
T1 - Synthesis and characterization of optically active helical polymers based on 2,5-di(4′-formylphenyl)styrene
AU - Zhu, Zhiguo
AU - Zhi, Junge
AU - Liu, Anhua
AU - Cui, Jiaxi
AU - Wan, Xinhua
AU - Chen, Xiaofang
AU - Zhou, Qifeng
PY - 2007/9
Y1 - 2007/9
N2 - 2, 5-Di (4′-formylphenyl) styrene was synthesized via Suzuki cross-coupling reaction of 2, 5-dibromostyrene and p-formylphenylboronic acid. In the presence of catalytic amount of glacial acetic acid, a pair of chiral nonracemic vinyl monomers, (+)-2,5-di {4′-[(N-(S)-α- methylbenzylimine)methylene]phenyl} styrene (M 1)and(-)-2,5-di {4′-[(N-(R)-α-methylbenzylimine) methylene] phenyl} styrene (M 2),was synthesized through the condensation reaction between 2, 5-di (4′-formylphenyl) styrene and optically pure α-methylbenzylamine. Optically active polymers were prepared via free radical polymerization of M 1 and M 2 initiated by AIBN or BPO depending on polymerization temperature. The results from specific optical rotation, UV-Vis absorption spectra and circular dichroism spectra indicated that the polymer obtained might adopt a helical conformation with a predominance of one helical screw sense. The polymerization condition had pronounced effects on the chiroptical properties of the polymers. Polymer with larger helical chirality was obtained when the polymerization was carried out in more polar aromatic media at higher temperature. Due to the steric hindrance of the bulky p-terphenyl groups, the main chain helical chirality formed during polymerization was thermally stable and displayed memory effect.
AB - 2, 5-Di (4′-formylphenyl) styrene was synthesized via Suzuki cross-coupling reaction of 2, 5-dibromostyrene and p-formylphenylboronic acid. In the presence of catalytic amount of glacial acetic acid, a pair of chiral nonracemic vinyl monomers, (+)-2,5-di {4′-[(N-(S)-α- methylbenzylimine)methylene]phenyl} styrene (M 1)and(-)-2,5-di {4′-[(N-(R)-α-methylbenzylimine) methylene] phenyl} styrene (M 2),was synthesized through the condensation reaction between 2, 5-di (4′-formylphenyl) styrene and optically pure α-methylbenzylamine. Optically active polymers were prepared via free radical polymerization of M 1 and M 2 initiated by AIBN or BPO depending on polymerization temperature. The results from specific optical rotation, UV-Vis absorption spectra and circular dichroism spectra indicated that the polymer obtained might adopt a helical conformation with a predominance of one helical screw sense. The polymerization condition had pronounced effects on the chiroptical properties of the polymers. Polymer with larger helical chirality was obtained when the polymerization was carried out in more polar aromatic media at higher temperature. Due to the steric hindrance of the bulky p-terphenyl groups, the main chain helical chirality formed during polymerization was thermally stable and displayed memory effect.
KW - Chiral vinyl monomer
KW - Free radical polymerization
KW - Helical conformation
KW - Optically active polymer
KW - Schiff base
KW - p-terphenyl group
UR - http://www.scopus.com/inward/record.url?scp=37749024437&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:37749024437
SN - 1000-3304
SP - 875
EP - 883
JO - Acta Polymerica Sinica
JF - Acta Polymerica Sinica
IS - 9
ER -