Synthesis and characterization of octa (aminophenyl) polyhedral silsesquioxane

Jian Ke Du; Rong Jie Yang

Synthesis and characterization of octa (aminophenyl) polyhedral silsesquioxane

Jian Ke Du^*, Rong Jie Yang

^*此作品的通讯作者

材料学院

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

3 引用（Scopus）

摘要

In the presence of FeCl₃·6H₂O/C catalyst, octa (nitrophenyl) polyhedral silsesquioxane (ONPS) was successfully reduced to octa (aminophenyl) polyhedral silsesquioxane (OAPS) using hydrazine hydrate with a yield of 93%. Structure and properties of OAPS are characterized by means of FTIR, NMR, elemental and thermal analysis. Its temperature corresponding to 5% weight loss is 338.8°C. This shows that OAPS has a high stability to heat. At the same time, mechanism of the reduction of ONPS by hydrazine catalyzed by FeCl₃/C was proposed.

源语言	英语
页（从-至）	358-361
页数	4
期刊	Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology
卷	27
期	4
出版状态	已出版 - 4月 2007

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title = "Synthesis and characterization of octa (aminophenyl) polyhedral silsesquioxane",

abstract = "In the presence of FeCl3·6H2O/C catalyst, octa (nitrophenyl) polyhedral silsesquioxane (ONPS) was successfully reduced to octa (aminophenyl) polyhedral silsesquioxane (OAPS) using hydrazine hydrate with a yield of 93%. Structure and properties of OAPS are characterized by means of FTIR, NMR, elemental and thermal analysis. Its temperature corresponding to 5% weight loss is 338.8°C. This shows that OAPS has a high stability to heat. At the same time, mechanism of the reduction of ONPS by hydrazine catalyzed by FeCl3/C was proposed.",

keywords = "Octa (aminophenyl) polyhedral silsesquioxane, Organic-inorganic hybrid materials, Reaction mechanism, Synthesis and characterization",

author = "Du, {Jian Ke} and Yang, {Rong Jie}",

year = "2007",

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language = "English",

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T1 - Synthesis and characterization of octa (aminophenyl) polyhedral silsesquioxane

AU - Du, Jian Ke

AU - Yang, Rong Jie

PY - 2007/4

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N2 - In the presence of FeCl3·6H2O/C catalyst, octa (nitrophenyl) polyhedral silsesquioxane (ONPS) was successfully reduced to octa (aminophenyl) polyhedral silsesquioxane (OAPS) using hydrazine hydrate with a yield of 93%. Structure and properties of OAPS are characterized by means of FTIR, NMR, elemental and thermal analysis. Its temperature corresponding to 5% weight loss is 338.8°C. This shows that OAPS has a high stability to heat. At the same time, mechanism of the reduction of ONPS by hydrazine catalyzed by FeCl3/C was proposed.

AB - In the presence of FeCl3·6H2O/C catalyst, octa (nitrophenyl) polyhedral silsesquioxane (ONPS) was successfully reduced to octa (aminophenyl) polyhedral silsesquioxane (OAPS) using hydrazine hydrate with a yield of 93%. Structure and properties of OAPS are characterized by means of FTIR, NMR, elemental and thermal analysis. Its temperature corresponding to 5% weight loss is 338.8°C. This shows that OAPS has a high stability to heat. At the same time, mechanism of the reduction of ONPS by hydrazine catalyzed by FeCl3/C was proposed.

KW - Octa (aminophenyl) polyhedral silsesquioxane

KW - Organic-inorganic hybrid materials

KW - Reaction mechanism

KW - Synthesis and characterization

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SN - 1001-0645

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JO - Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology

JF - Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology

IS - 4

ER -

Synthesis and characterization of octa (aminophenyl) polyhedral silsesquioxane

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